Oxone®, 单过硫酸 (过硫酸钾)

• 产品号: 89892
• CAS号: 70693-62-8
• 分子式: H3K5O18S4
• 分子量: 614.76452

产品别名

• 标题: Oxone®, monopersulfate
• IUPAC标准名: pentapotassium bis(O-sulfonoperoxoatooxidanol) hydrogen sulfate sulfate
• IUPAC传统名: pentapotassium bis(sulfodioxidanide) hydrogensulfate sulfate
• 别名: Potassium peroxymonosulfate; Potassium monopersulfate triple salt

产品登记号

• MDL号: MFCD00040551
• EC号: 274-778-7
• CAS号: 70693-62-8

产品性质

• 外观: Granular
• 密度: 1.15
• GHS危险声明: H272-H301-H317-H334-H314-H318
• 欧盟危险性物质标志: X
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 欧盟危险性物质标志: 氧化性(Oxidising) (O)
• GHS警示性声明: P221-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A
• 危险公开号: 8-22-34-42/43
• 安全公开号: 17-22-26-36/37/39-45
• 保存注意事项: Hygroscopic
• TSCA收录: 是
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN3084
• 联合国危险货物包装类别(PG): II

参考文献

• Versatile oxidizing agent. For use in the generation of dioxiranes. Primary arylamines in aqueous acetone buffered with bicarbonate give nitro compounds in good yield: Tetrahedron Lett., 36, 2377 (1995). Boronic acids and boronic esters are oxidized to phenols under similar conditions: Tetrahedron Lett., 36, 5117 (1995). Secondary amines are converted to nitroxide radicals in the presence of acetone and a phosphate buffer: Tetrahedron Lett., 36, 5547 (1995). Preferred co-oxidant for generation of dioxiranes from ketones; see Acetone, L10407. For use in a practical epoxidation of olefins using acetone in EtOAc-H₂O, see: Org. Process. Res. Dev., 6, 405 (2002).
• For a brief feature on the reagent, see: Synlett, 1178 (2002).
• Oxone is a registered trademark of E. I. Dupont de Nemours & Co., Inc.