高碘酸钠

• 产品号: 13798
• CAS号: 7790-28-5
• 分子式: INaO4
• 分子量: 213.89184
• 纯 度: 98%

产品别名

• 标题: Sodium metaperiodate
• IUPAC标准名: sodium periodate
• IUPAC传统名: sodium periodate
• 别名: Sodium periodate

产品登记号

• CAS号: 7790-28-5
• 默克索引号: 148640
• EC号: 232-197-6
• MDL号: MFCD00003534

产品性质

• 纯度: 98%
• 外观: Powder
• 密度: 3.86
• 熔点: 300°C dec.
• 溶解度: Soluble in water and acids
• GHS危险声明: H272-H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 欧盟危险性物质标志: 氧化性(Oxidising) (O)
• GHS警示性声明: P221-P210-P305+P351+P338-P302+P352-P405-P501A
• 危险公开号: 8-36/37/38
• RTECS编号: SD4550000
• 安全公开号: 17-26-37
• 保存注意事项: Hygroscopic
• TSCA收录: 是
• 联合国危险货物等级: 5.1
• 联合国危险货物编号: UN1479
• 联合国危险货物包装类别(PG): II

参考文献

• For review of use in the cleavage of 1,2-diols to carbonyl compounds, see: Synthesis, 229 (1974). For application to the high-yield, racemization-free preparation of the useful intermediate isopropylidene-D-glyceraldehyde, see: Synth. Commun., 18, 337 (1988). See also: Org. Synth. Coll., 9, 450, 454 (1998).
• This reaction can be extended to the cleavage of alkenes, by use in conjunction with a reagent for the hydroxylation of alkenes, which can be regenerated by reoxidation by periodate. For use in combination with KMnO₄ (Lemieux-von Rudloff reagent), see: Can. J. Chem., 33, 1701, 1710 (1955), for cleavage of a steroidal enone, see: Org. Synth. Coll., 6, 690 (1988). The combination with OsO₄ is known as the Lemieux-Johnson reagent: J. Org. Chem., 21, 478 (1956); Synthesis, 45 (1989).
• For use in the in situ regeneration of RuO₄,see Ruthenium(III) chloride hydrate, 11043.
• Useful for selective oxidation of sulfides to sulfoxides; see, for example: Org. Synth. Coll., 9, 63 (1998).
• Alkyl halides, on heating with NaIO₄ in DMF, can be oxidized to aldehydes or ketones: Tetrahedron Lett., 44, 1375 (2003). For use, in the presence of Dibenzo-18-crown-6, A13133, in the oxidative decarboxylation of arylacetic acids to benzaldehydes and of phenacyl bromides to benzoic acids, see: Indian J. Chem. B, 35B, 151 (1996).