氯化亚铜(I)

• 产品号: 11871
• CAS号: 7758-89-6
• 分子式: ClCu
• 分子量: 98.999
• 纯 度: 97%

产品别名

• 标题: Copper(I) chloride
• IUPAC标准名: λ^1-copper(1+) ion chloride
• IUPAC传统名: λ^1-copper(1+) ion chloride

产品登记号

• CAS号: 7758-89-6
• EC号: 231-842-9
• MDL号: MFCD00010971
• 默克索引号: 142660

产品性质

• 纯度: 97%
• 外观: Powder
• 沸点: 1490°C
• 密度: 4.14
• 熔点: 430°C
• 折射率: 1.93
• GHS危险声明: H400-H410-H302
• 欧盟危险性物质标志: X
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• GHS警示性声明: P273-P264-P270-P301+P312-P330-P501A
• 危险公开号: 22-50/53
• RTECS编号: GL6990000
• 安全公开号: 22-60-61
• 保存注意事项: Air & Moisture Sensitive
• TSCA收录: 是
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN2802
• 联合国危险货物包装类别(PG): III

参考文献

• For use in the oxidative cleavage of phenols, see Catechol, A10164.
• For use in the Simmons-Smith cyclopropanation reaction, see Dibromomethane, A10456.
• A 1:1 mixture with 2,2'-bipyridine catalyzes the cyclization of allyl trichloroacetamides to -lactams: J. Org. Chem ., 58, 464 (1993).
• Catalyst for the Sandmeyer preparation of aryl chlorides; for use in the related conversion of aryldiazonium salts to sulfonyl chlorides with SO₂, see: Org. Synth. Coll., 7, 508 (1990).
• Used in combination with Tris(3,6-dioxaheptyl)amine, L13544, in the Ullmann aryl ether synthesis: J. Org. Chem., 50, 3717 (1985), and an improved N-arylation of amides: Synthesis, 312 (1989).
• In combination with TMEDA, promotes the Hay (improved Glaser) coupling of terminal acetylenes: Org. Synth. Coll., 8, 63 (1993).