λ1-copper(1+) ion chloride

• ChemBase编号: 302849
• 分子式: ClCu
• 平均质量: 98.999
• 单一同位素质量: 97.89845018
• SMILES: [Cl-].[Cu+]
• Canonical SMILES: [Cl-].[Cu+]
• InChI: InChI=1S/ClH.Cu/h1H;/q;+1/p-1
• InChIKey: OXBLHERUFWYNTN-UHFFFAOYSA-M

名称和登记号

名称

• IUPAC标准名: λ^1-copper(1+) ion chloride
• IUPAC传统名: λ^1-copper(1+) ion chloride
• 别名: 氯化亚铜(I), ACS; 氯化亚铜(I); Copper(I) chloride, ACS; Copper(I) chloride

登记号

• CAS号: 7758-89-6
• EC号: 231-842-9
• MDL号: MFCD00010971
• 默克索引号: 142660

理论计算性质

• Acid pKa: -7.0
• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 0.8327582
• LogD (pH = 7.4): 0.8327582
• Log P: 0.6123387
• 摩尔折射率: 5.6156 cm^3
• 极化性: 2.1090326 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: Sparingly soluble in water. Insoluble in alcohol and acetone. Soluble in HCl, and NH4OH
• 外观: -80 Mesh Powder; Powder
• 熔点: 430°C
• 沸点: 1490°C
• 密度: 4.14
• 折射率: 1.93

安全信息

• 保存注意事项: Air & Moisture Sensitive
• RTECS编号: GL6990000
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N); X
• 联合国危险货物编号: UN2802
• 联合国危险货物等级: 8
• 联合国危险货物包装类别(PG): III
• 危险公开号: 22-50/53
• 安全公开号: 22-60-61
• TSCA收录: 是
• GHS危险品标识: GHS07; GHS09
• GHS危险声明: H400-H410-H302
• GHS警示性声明: P273-P264-P270-P301+P312-P330-P501A

产品相关信息

• 纯度: 90+%; 97%; 99% (metals basis); 99.999% (metals basis)

参考文献

• For use in the oxidative cleavage of phenols, see Catechol, A10164.
• For use in the Simmons-Smith cyclopropanation reaction, see Dibromomethane, A10456.
• A 1:1 mixture with 2,2'-bipyridine catalyzes the cyclization of allyl trichloroacetamides to -lactams: J. Org. Chem ., 58, 464 (1993).
• Catalyst for the Sandmeyer preparation of aryl chlorides; for use in the related conversion of aryldiazonium salts to sulfonyl chlorides with SO₂, see: Org. Synth. Coll., 7, 508 (1990).
• Used in combination with Tris(3,6-dioxaheptyl)amine, L13544, in the Ullmann aryl ether synthesis: J. Org. Chem., 50, 3717 (1985), and an improved N-arylation of amides: Synthesis, 312 (1989).
• In combination with TMEDA, promotes the Hay (improved Glaser) coupling of terminal acetylenes: Org. Synth. Coll., 8, 63 (1993).