溴-三吡咯烷基磷代六氟磷酸酯

• 产品号: L19384
• CAS号: 132705-51-2
• 分子式: C12H24BrF6N3P2
• 分子量: 466.1810012
• 纯 度: 97%

产品别名

• 标题: Bromotri(1-pyrrolidinyl)phosphonium hexafluorophosphate
• IUPAC标准名: bromotris(pyrrolidin-1-yl)phosphanium; hexafluoro-λ^5-phosphanuide
• IUPAC传统名: bromotris(pyrrolidin-1-yl)phosphanium hexafluorophosphate
• 别名: PyBroP

产品登记号

• Beilstein号: 7845702
• EC号: 000-000-0
• MDL号: MFCD00077412
• CAS号: 132705-51-2

产品性质

• 纯度: 97%
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• GHS警示性声明: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 危险公开号: 36/37/38
• 安全公开号: 26-37
• 保存注意事项: Moisture Sensitive
• TSCA收录: 否

参考文献

• Efficient peptide coupling agent for N-methylated amino esters for which coupling with a number of conventional reagents has proved ineffective or slow, and giving superior results to 1H-Benzotriazol-1-yloxytri(1-pyrrolidinyl)phosphonium hexafluorophosphate, B25251, in this type of reaction: J. Org. Chem., 59, 2437 (1994). See Appendix 6.
• Can also be used to activate formamides, e.g. reaction of DMF with primary amines to yield formamidines: Tetrahedron Lett., 40, 5487 (1999).