氯化铟(III), 无水

• 产品号: L18758
• CAS号: 10025-82-8
• 分子式: Cl3In
• 分子量: 221.177
• 纯 度: 98+%

产品别名

• 标题: Indium(III) chloride, anhydrous
• IUPAC标准名: indium(3+) ion trichloride
• IUPAC传统名: indium(3+) ion trichloride

产品登记号

• 默克索引号: 144958
• EC号: 233-043-0
• MDL号: MFCD00011058
• CAS号: 10025-82-8

产品性质

• 纯度: 98+%
• 沸点: 800°C
• 密度: 3.460
• 熔点: 586°C
• GHS危险声明: H301-H314-H318
• 欧盟危险性物质标志: X
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• GHS警示性声明: P260-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A
• 危险公开号: 22-34
• RTECS编号: NL1400000
• 安全公开号: 20-26-36/37/39-45-60
• 保存注意事项: Hygroscopic
• TSCA收录: 是
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN3260
• 联合国危险货物包装类别(PG): II

参考文献

• Promotes efficient azidolysis of ɑ?-epoxy carboxyl derivatives in water at pH 4, with results superior to Yb(OTf)₃ or Sc(OTf)₃: J. Org. Chem., 66, 3554 (2001).
• Indium enolates are readily formed by transmetallation of Li enolates. These undergo Reformatsky-type reactions with aldehydes to give ?-hydroxy esters. ɑ-Bromo enolates give Darzens-type ɑ?-epoxy carbonyl compounds: J. Chem. Soc., Perkin 1, 825 (2000).
• The combination with NaBH₄ has been reported to be an effective radical reducing system, replacing the environmentally unfavorable TBTH (Tri-n-butyltin hydride, A13298), e.g. in dehalogenation and cyclization reactions: J. Am. Chem. Soc., 124, 906 (2002).
• In combination with Triethylsilane, A10320 and a radical initiator, generates a radical reagent, analogous to Tri-n-butyltin hydride, A13298: Org. Lett., 6, 4981 (2004).
• For a brief feature on InCl₃, see: Synlett, 531 (2002). For reviews of the use of In compounds in organic synthesis, see: Eur. J. Org. Chem., 2347 (2000); J. Chem. Soc., Perkin 1, 3015 (2000).
• Mild, water tolerant Lewis acid catalyst, e.g. in allylation reactions of sensitive aldehydes with allyltributyltin: J. Org Chem., 61, 105 (1996). The allylstannane can also be generated in situ from the allyl halidein water: Tetrahedron Asym., 7, 1535 (1996). Catalyzes the Mukaiyama aldol reaction, under either solvent-free conditions: Tetrahedron Lett., 39, 1579 (1998), or in water: Chem. Commun., 1819 (1996); 861 (1998); Tetrahedron Lett., 38, 3465 (1997).For Diels-Alder reactions in water, see: Chem. Commun., 2315 (1996).
• In combination with a dithiol, catalyzes the efficient transthioacetalization of acetals to dithioacetals: Synlett, 727 (2002).
• Aldoximes can be dehydrated to nitriles; ketoximes undergo the Beckmann rearrangement to amides: Chem. Commun., 1196 (2000).
• Catalyst for conjugate addition of indoles to electron-deficient alkenes: Synthesis, 2165 (2001):