indium(3+) ion trichloride

• ChemBase编号: 107321
• 分子式: Cl3In
• 平均质量: 221.177
• 单一同位素质量: 219.81043604
• SMILES: [Cl-].[Cl-].[Cl-].[In+3]
• Canonical SMILES: [Cl-].[Cl-].[Cl-].[In+3]
• InChI: InChI=1S/3ClH.In/h3*1H;/q;;;+3/p-3
• InChIKey: PSCMQHVBLHHWTO-UHFFFAOYSA-K

名称和登记号

名称

• IUPAC标准名: indium(3+) ion trichloride
• IUPAC传统名: indium(3+) trichloride; indium(3+) ion trichloride
• 别名: 氯化铟(III), 超干; 氯化铟(III), 无水; 氯化铟, 无水; INDIUM CARBONATE; Indium(III) chloride, ultra dry; Indium(III) chloride, anhydrous

登记号

• CAS号: 13465-10-6; 10025-82-8
• EC号: 233-043-0; 236-693-3
• MDL号: MFCD00011058
• 默克索引号: 144958
• PubChem SID: 162094854
• PubChem CID: 159675

理论计算性质

• Acid pKa: -7.0
• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 0.8327582
• LogD (pH = 7.4): 0.8327582
• Log P: 0.6123387
• 摩尔折射率: 5.6156 cm^3
• 极化性: 2.1090326 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: Soluble in water
• 外观: Crystalline; Powder, Ampouled under argon
• 熔点: 586°C
• 沸点: 800°C
• 密度: 3.460

安全信息

• 保存注意事项: Hygroscopic
• RTECS编号: NL1400000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); X
• 联合国危险货物编号: UN3260
• 联合国危险货物等级: 8
• 联合国危险货物包装类别(PG): II
• 危险公开号: 22-34
• 安全公开号: 20-26-36/37/39-45-60
• TSCA收录: 是
• GHS危险品标识: GHS05; GHS06
• GHS危险声明: H301-H314-H318
• GHS警示性声明: P260-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A

产品相关信息

• 纯度: 98+%; 99.99% (metals basis); 99.999% (metals basis)

详细说明

MP Biomedicals - 05203323

MP Biomedicals Rare Chemical collection

参考文献

• Promotes efficient azidolysis of ɑ?-epoxy carboxyl derivatives in water at pH 4, with results superior to Yb(OTf)₃ or Sc(OTf)₃: J. Org. Chem., 66, 3554 (2001).
• Indium enolates are readily formed by transmetallation of Li enolates. These undergo Reformatsky-type reactions with aldehydes to give ?-hydroxy esters. ɑ-Bromo enolates give Darzens-type ɑ?-epoxy carbonyl compounds: J. Chem. Soc., Perkin 1, 825 (2000).
• The combination with NaBH₄ has been reported to be an effective radical reducing system, replacing the environmentally unfavorable TBTH (Tri-n-butyltin hydride, A13298), e.g. in dehalogenation and cyclization reactions: J. Am. Chem. Soc., 124, 906 (2002).
• In combination with Triethylsilane, A10320 and a radical initiator, generates a radical reagent, analogous to Tri-n-butyltin hydride, A13298: Org. Lett., 6, 4981 (2004).
• For a brief feature on InCl₃, see: Synlett, 531 (2002). For reviews of the use of In compounds in organic synthesis, see: Eur. J. Org. Chem., 2347 (2000); J. Chem. Soc., Perkin 1, 3015 (2000).
• Mild, water tolerant Lewis acid catalyst, e.g. in allylation reactions of sensitive aldehydes with allyltributyltin: J. Org Chem., 61, 105 (1996). The allylstannane can also be generated in situ from the allyl halidein water: Tetrahedron Asym., 7, 1535 (1996). Catalyzes the Mukaiyama aldol reaction, under either solvent-free conditions: Tetrahedron Lett., 39, 1579 (1998), or in water: Chem. Commun., 1819 (1996); 861 (1998); Tetrahedron Lett., 38, 3465 (1997).For Diels-Alder reactions in water, see: Chem. Commun., 2315 (1996).
• In combination with a dithiol, catalyzes the efficient transthioacetalization of acetals to dithioacetals: Synlett, 727 (2002).
• Aldoximes can be dehydrated to nitriles; ketoximes undergo the Beckmann rearrangement to amides: Chem. Commun., 1196 (2000).
• Catalyst for conjugate addition of indoles to electron-deficient alkenes: Synthesis, 2165 (2001):