四氢呋喃硼烷,1M 在四氢呋喃溶剂中,以5mmol NaBH

• 产品号: L13961
• CAS号: 14044-65-6
• 分子式: C4H11BO
• 分子量: 85.94054

产品别名

• 标题: Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4
• IUPAC标准名: oxolane borane
• IUPAC传统名: tetrahydrofuran borane
• 别名: BTHF

产品登记号

• EC号: 237-881-8
• Beilstein号: 3668402
• CAS号: 14044-65-6
• MDL号: MFCD00012429

产品性质

• 浓度: 1M soln. in THF
• 密度: 0.878
• 闪点: -21°C(-8°F)
• GHS危险声明: H225-H260-H318-H315-H351-H335-H303
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• GHS警示性声明: P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501A
• 危险公开号: 11-14/15-19-37/38-41
• 安全公开号: 7/8-9-16-23-26-30-33-36/37/39-43-60
• 保存注意事项: Air & Moisture Sensitive
• TSCA收录: 是
• 联合国危险货物等级: 4.3
• 联合国危险货物编号: UN3148
• 联合国危险货物包装类别(PG): I

参考文献

• Hydroboration, followed by reaction of the trialkylborane with a diazoketone to give a homologated ketone: Org. Synth. Coll., 6, 919 (1988). In situ generation of "disiamyl" borane from 2-methyl-2-butene, and use of this reagent in selective hydroboration reactions: Org. Synth. Coll., 7, 258 (1990). Preparation of di-3-pinanylborane from (-)-ɑ-pinene, and its use in asymmetric hydroborations, see: Org. Synth. Coll., 7,339 (1990).
• For other reactions of borane, see Borane-dimethyl sulfide complex, L07705.
• Examples of hydroboration reactions:
• For use in the reduction of carboxylic acids to alcohols, see: Org. Synth. Coll., 7, 221 (1990).