苯基三甲基三溴化铵

• 产品号: A15326
• CAS号: 4207-56-1
• 分子式: C9H14Br3N
• 分子量: 375.92616
• 纯 度: 97%

产品别名

• 标题: Phenyltrimethylammonium tribromide
• IUPAC标准名: N,N,N-trimethylanilinium dibromane bromide
• IUPAC传统名: Brom tetrabutylammonium tribromide bromide
• 别名: Trimethylphenylammonium tribromide; N,N,N-Trimethylanilinium tribromide

产品登记号

• CAS号: 4207-56-1
• EC号: 224-127-8
• Beilstein号: 3919459
• MDL号: MFCD00011789

产品性质

• 纯度: 97%
• 熔点: 112-117°C
• GHS危险声明: H314-H318
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• GHS警示性声明: P280-P303+P361+P353-P305+P351+P338-P310
• 危险公开号: 34
• 安全公开号: 26-36/37/39-45
• 保存注意事项: Hygroscopic
• TSCA收录: 是
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN3261
• 联合国危险货物包装类别(PG): II

参考文献

• Reagent for the selective ɑ-bromination of acetals with good stability and solubility in organic solvents such as THF: Tetrahedron Lett., 24 (1959); Bull. Soc. Chim. Fr., 1822 (1961); 90 (1962). For example of use in a one-pot ɑ-bromoacetalization of carbonyl compounds in high yields, see: Synthesis, 309 (1982).
• For example of selective ɑ-monobromination of ketones, see: Org. Synth. Coll., 6, 175 (1988). Silyl enol ethers are also ɑ-brominated with this reagent to give ɑ-bromo enones: Synlett, 651 (1994).
• Tosylhydrazones have been oxidized to N-alkenyl-N'-tosyldiazenes: J. Org. Chem., 39, 826 (1974).
• Catalyses the aziridination of alkenes by Chloramine-T trihydrate, A12044: J. Am. Chem. Soc., 120, 6844 (1998).