氯化锑(III)

• 产品号: A11944
• CAS号: 10025-91-9
• 分子式: Cl3Sb
• 分子量: 228.119
• 纯 度: 99+%

产品别名

• 标题: Antimony(III) chloride
• IUPAC标准名: antimony(3+) ion trichloride
• IUPAC传统名: antimony(3+) ion trichloride
• 别名: Antimony trichloride

产品登记号

• 默克索引号: 14707
• MDL号: MFCD00011212
• CAS号: 10025-91-9
• EC号: 233-047-2

产品性质

• 纯度: 99+%
• 沸点: 223.5°C
• 密度: 3.14
• 熔点: 73.4°C
• GHS危险声明: H314-H411
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• GHS警示性声明: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
• 危险公开号: 34-51/53
• RTECS编号: CC4900000
• 安全公开号: 26-45-61
• 保存注意事项: Moisture Sensitive
• TSCA收录: 是
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN1733
• 联合国危险货物包装类别(PG): II

参考文献

• Superior to other Lewis acids for promoting the palladium(0)-catalyzed conjugate arylation of ɑ?-unsaturated ketones and aldehydes with tetraphenyl borate and arylboronic acids: J. Org. Chem., 60, 883 (1995). Effective catalyst for conversion of epoxides to thiiranes with (NH₄)₂SCN: Indian J. Chem., 38B, 605 (1999).
• Mild Lewis acid catalyst.
• Preferred catalyst for fluoro-Pummerer reaction with DAST (Diethylaminosulfur trifluoride, A11992) for the formation of ɑ-fluoro thioethers from sulfoxides: Tetrahedron Lett., 29, 5729 (1988); J. Org. Chem., 55, 4757 (1990); Org. Synth. Coll., 9, 446 (1998). Direct conversion of thioethers to the ɑ-fluoro analogues has also been reported: J. Org. Chem., 58, 3800 (1993).