antimony(3+) ion trichloride

• ChemBase编号: 295225
• 分子式: Cl3Sb
• 平均质量: 228.119
• 单一同位素质量: 225.81037304
• SMILES: [Cl-].[Cl-].[Cl-].[Sb+3]
• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Sb+3]
• InChI: InChI=1S/3ClH.Sb/h3*1H;/q;;;+3/p-3
• InChIKey: FAPDDOBMIUGHIN-UHFFFAOYSA-K

名称和登记号

名称

• IUPAC标准名: antimony(3+) ion trichloride
• IUPAC传统名: antimony(3+) ion trichloride
• 别名: 氯化锑(III), ACS; 氯化锑(III), 超干; 氯化锑(III); 氯化锑(III), Puratronic?; Antimony(III) chloride, ACS; Antimony(III) chloride, ultra dry; Antimony trichloride; Antimony(III) chloride; Antimony(III) chloride, Puratronic®

登记号

• CAS号: 10025-91-9
• EC号: 233-047-2
• MDL号: MFCD00011212
• 默克索引号: 14707
• PubChem SID: 180680756
• PubChem CID: 10220195

理论计算性质

• Acid pKa: -7.0
• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 0.8327582
• LogD (pH = 7.4): 0.8327582
• Log P: 0.6123387
• 摩尔折射率: 5.6156 cm^3
• 极化性: 2.1090326 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: Soluble in water with hydrolysis to SbOCl. Soluble in HCl solution, alcohol, benzene, carbon disulfide, dioxane, chloroform, ether, acetone, carbon tetrachloride. Insoluble in organic bases
• 外观: Crystalline; Crystalline Aggregates; Crystals, Ampouled under argon
• 熔点: 73.4°C
• 沸点: 223.5°C
• 密度: 3.14

安全信息

• 保存注意事项: Moisture Sensitive
• RTECS编号: CC4900000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 环境危害性(Nature polluting) (N)
• 联合国危险货物编号: UN1733
• 联合国危险货物等级: 8
• 联合国危险货物包装类别(PG): II
• 危险公开号: 34-51/53
• 安全公开号: 26-45-61
• TSCA收录: 是
• GHS危险品标识: GHS05; GHS09
• GHS危险声明: H314-H411
• GHS警示性声明: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A

产品相关信息

• 纯度: 99.0% min; 99.9% (metals basis); 99.999% (metals basis); 99+%

参考文献

• Superior to other Lewis acids for promoting the palladium(0)-catalyzed conjugate arylation of ɑ?-unsaturated ketones and aldehydes with tetraphenyl borate and arylboronic acids: J. Org. Chem., 60, 883 (1995). Effective catalyst for conversion of epoxides to thiiranes with (NH₄)₂SCN: Indian J. Chem., 38B, 605 (1999).
• Mild Lewis acid catalyst.
• Preferred catalyst for fluoro-Pummerer reaction with DAST (Diethylaminosulfur trifluoride, A11992) for the formation of ɑ-fluoro thioethers from sulfoxides: Tetrahedron Lett., 29, 5729 (1988); J. Org. Chem., 55, 4757 (1990); Org. Synth. Coll., 9, 446 (1998). Direct conversion of thioethers to the ɑ-fluoro analogues has also been reported: J. Org. Chem., 58, 3800 (1993).