丙烯腈

• 产品号: A13058
• CAS号: 107-13-1
• 分子式: C3H3N
• 分子量: 53.06262
• 纯 度: 99+%, stab. with ca 40ppm 4-methoxyphenol

产品别名

• 标题: Acrylonitrile
• IUPAC标准名: prop-2-enenitrile
• IUPAC传统名: acrylonitrile
• 别名: Propenenitrile; Vinyl cyanide

产品登记号

• 默克索引号: 14131
• CAS号: 107-13-1
• EC号: 203-466-5
• MDL号: MFCD00001927
• Beilstein号: 605310

产品性质

• 纯度: 99+%, stab. with ca 40ppm 4-methoxyphenol
• 沸点: 77-78°C
• 密度: 0.806
• 闪点: 0°C(32°F)
• 熔点: -84°C
• 折射率: 1.3910
• GHS危险声明: H225-H301-H311-H331-H315-H317-H335-H350-H318-H411
• 欧盟危险性物质标志: 有毒(Toxic) (T)
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• GHS警示性声明: P210-P301+P310-P303+P361+P353-P305+P351+P338-P361-P405-P501A
• 危险公开号: 45-11-23/24/25-37/38-41-43-51/53
• RTECS编号: AT5250000
• 安全公开号: 53-9-16-45-61
• 保存注意事项: Light Sensitive
• TSCA收录: 是
• 联合国危险货物等级: 3
• 联合国危险货物编号: UN1093
• 联合国危险货物包装类别(PG): I

参考文献

• Free radical alkylation, acylation and arylation reactions also occur in the presence of t-butyl hydroperoxide and a Cu(II) catalyst: J. Chem. Soc., Chem. Commun., 1399 (1995). Several other free radical procedures have been reported involving intramolecular homolytic aromatic substitution to give carbocyclic and heterocyclic systems: Tetrahedron Lett., 36, 4307 (1995):
  
• The Stetter reaction (conjugate addition of aryl aldehydes) catalyzed by CN^-, is exemplified by the addition of pyridine-3-carboxaldehyde to acrylonitrile to give 4-oxo-4-(3-pyridyl)butyronitrile: Org. Synth. Coll., 6, 866 (1988). See also 3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazolium chloride, L08750.
• The reaction is also applicable to acrylate esters and vinyl ketones; with acrylonitrile and phenoxyacetic acid, tetrahydrobenzopyran-4-carbonitrile is obtained in 41% yield.