三苯基膦-氢化铜六聚物

• 产品号: 364975
• CAS号: 33636-93-0
• 分子式: C108H90Cu6P6
• 分子量: 1954.988766
• 纯 度: 90%

产品别名

• 标题: (Triphenylphosphine)copper hydride hexamer
• IUPAC标准名: hexakis(triphenylphosphane) hexakis(λ^1-copper)
• IUPAC传统名: hexakis(triphenylphosphine) hexakis(λ^1-copper)
• 别名: Stryker’s reagent; Cuprous hydride triphenylphosphine hexamer; Hydrido(triphenylphosphine)copper(I) hexamer; Triphenylphosphine-Copper(I) hydride Hexamer; Stryker 试剂; 三苯基磷酸亚酮六聚体

产品登记号

• PubChem SID: 24862472
• CAS号: 33636-93-0
• MDL号: MFCD00221518

产品性质

• 线性分子式: [(C6H5)3PCuH]6
• 纯度: 90%
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26-36
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Packaging
1, 5 g in glass bottle
Application
Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates1
• Chemoselective preparation of alcohols via hydrogenation of aldehydes2
• 1,2-addition/transmetalation reactions3
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins4
• Hydrosilylation reactions5
• Chiral hydrogenation reactions6
• Hydrostannation of activated alkynes7
Useful synthetic applications include stoichiometric and catalytic hydrogenations, chemoselective conjugate reductions, as well as regiospecific and stereoselectiveconjugate hydride reductions.

详细说明 (简体中文)

包装
1, 5 g in glass bottle
Application
Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates1
• Chemoselective preparation of alcohols via hydrogenation of aldehydes2
• 1,2-addition/transmetalation reactions3
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins4
• Hydrosilylation reactions5
• Chiral hydrogenation reactions6
• Hydrostannation of activated alkynes7
可用于合成用途包括化学计量和催化氢化反应、化学选择共轭还原以及区域专一和立体选择共轭氢化物还原反应。