hexakis(triphenylphosphane) hexakis(λ1-copper)

• ChemBase编号: 129635
• 分子式: C108H90Cu6P6
• 平均质量: 1954.988766
• 单一同位素质量: 1950.12440766
• SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.[Cu].[Cu].[Cu].[Cu].[Cu].[Cu]
• Canonical SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.[Cu].[Cu].[Cu].[Cu].[Cu].[Cu]
• InChI: InChI=1S/6C18H15P.6Cu/c6*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;;;/h6*1-15H
• InChIKey: KVBHFBAACGHMKE-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: hexakis(triphenylphosphane) hexakis(λ^1-copper)
• IUPAC传统名: hexakis(triphenylphosphine) hexakis(λ^1-copper)
• 别名: Stryker 试剂; 三苯基磷酸亚酮六聚体; 三苯基膦-氢化铜六聚物; 三苯基膦-氢化铜六聚体(I); Stryker's reagent; Hydrido(triphenylphosphine)copper(I) hexamer; Triphenylphosphine-Copper(I) hydride Hexamer; Cuprous hydride triphenylphosphine hexamer; Stryker’s reagent; (Triphenylphosphine)copper hydride hexamer; Triphenylphosphine-copper(I) hydride Hexamer

登记号

• CAS号: 33636-93-0
• MDL号: MFCD00221518
• PubChem SID: 24889794; 24862472; 162223924
• PubChem CID: 12181933; 11982471
• 维基百科标题: Stryker's_reagent

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 5.1066
• LogD (pH = 7.4): 5.1066
• Log P: 5.1066
• 摩尔折射率: 81.6229 cm^3
• 极化性: 32.34495 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 18
• 里宾斯基五规则: false

分子性质

安全信息

• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 德国WGK号: 3
• 危险公开号: 36/37/38
• 安全公开号: 26-36
• GHS危险品标识: GHS07
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• GHS警示性声明: P261-P305 + P351 + P338
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves

产品相关信息

• 纯度: 90%
• 级别: purum
• 线性分子式: [(C6H5)3PCuH]6

详细说明

Sigma Aldrich - 364975

包装
1, 5 g in glass bottle
Application
Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates1
• Chemoselective preparation of alcohols via hydrogenation of aldehydes2
• 1,2-addition/transmetalation reactions3
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins4
• Hydrosilylation reactions5
• Chiral hydrogenation reactions6
• Hydrostannation of activated alkynes7
可用于合成用途包括化学计量和催化氢化反应、化学选择共轭还原以及区域专一和立体选择共轭氢化物还原反应。

Sigma Aldrich - 93099

Other Notes
还原剂，用于生成羰基化合物的 α,β-不饱和羰基化合物的选择还原反应8,9,10,11；催化剂，用于氢的还原反应12
Application
Catalyst for:
• Conjugate reduction of ortho-substituted cinnamic esters to form copper enolates1
• Chemoselective preparation of alcohols via hydrogenation of aldehydes2
• 1,2-addition/transmetalation reactions3
• Synthesis of monomer for preparation of phosphorus- and silicon-containing epoxy resins4
• Hydrosilylation reactions5
• Chiral hydrogenation reactions6
• Hydrostannation of activated alkynes7