1,2-亚苯基-次氯酸化膦

• 产品号: 155764
• CAS号: 1641-40-3
• 分子式: C6H4ClO2P
• 分子量: 174.521521
• 纯 度: 97%

产品别名

• 标题: o-Phenylene phosphorochloridite
• IUPAC标准名: 2-chloro-2H-1,3,2-benzodioxaphosphole
• IUPAC传统名: 2-chloro-1,3,2-benzodioxaphosphole
• 别名: Cyclic o-phenylene phosphorochloridite; Phosphorochloridous acid orthophenylene ester; 2-Chloro-1,3,2-benzodioxaphosphole; 2-氯-1,3,2-苯并二氧环磷烯; o-Phenylene chlorophosphite; Chloro(1,2-phenylenedioxy)phosphine; Pyrocatechol phosphoryl chloride

产品登记号

• MDL号: MFCD00005853
• PubChem SID: 24849564
• CAS号: 1641-40-3
• EC号: 216-690-3
• Beilstein号: 135455

产品性质

• Empirical Formula (Hill Notation): C6H4ClO2P
• 纯度: 97%
• 沸点: 80 °C/20 mmHg(lit.)
• 密度: 1.466 g/mL at 25 °C(lit.)
• 闪点: 110 °C
• 闪点: 230 °F
• 熔点: 30-35 °C(lit.)
• 折射率: n20/D 1.571(lit.)
• GHS警示词: Danger
• GHS危险声明: H314
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS警示性声明: P280-P305 + P351 + P338-P310
• RID/ADR: UN 3261 8/PG 2
• 危险公开号: 34
• 安全公开号: 26-36/37/39-45
• 联合国危险货物等级: 8
• 联合国危险货物编号: 3261
• 联合国危险货物包装类别(PG): 2
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Packaging
10 g in glass bottle
Application

• Catalyst in synthesis of bakkane sesquiterpenes1
• Reactant in reversible halogen-halogen ligand substitution at room temperature, and in irreversible halogen-O substitution at higher temperatures2
• Reactant in preparation of gold(I) trimethoxybenzonitrile phosphine isolated precatalysts3
• Reactant for preparation of pyrroles by TMSOTf-catalyzed Arbuzov reaction4
• Phosphorylation agent5
• Reactant for reparation of vinyl-substituted spirophosphoranes and vinylphosphonates via Markovnikov addition6

详细说明 (简体中文)

包装
10 g in glass bottle
Application

• Catalyst in synthesis of bakkane sesquiterpenes1
• Reactant in reversible halogen-halogen ligand substitution at room temperature, and in irreversible halogen-O substitution at higher temperatures2
• Reactant in preparation of gold(I) trimethoxybenzonitrile phosphine isolated precatalysts3
• Reactant for preparation of pyrroles by TMSOTf-catalyzed Arbuzov reaction4
• Phosphorylation agent5
• Reactant for reparation of vinyl-substituted spirophosphoranes and vinylphosphonates via Markovnikov addition6