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9-硼双环[3.3.1]壬烷 溶液_分子结构_CAS_280-64-8)
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9-硼双环[3.3.1]壬烷 溶液

产品号 151076 公司名称 Sigma Aldrich
CAS号 280-64-8 公司网站 http://www.sigmaaldrich.com
分子式 C8H15B 电 话 1-800-521-8956
分子量 122.0157 传 真
纯 度 电子邮件
保 存 Chembase数据库ID: 140672

产品价格信息

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产品别名

标题
9-Borabicyclo[3.3.1]nonane solution
IUPAC标准名
(1s,5s)-9-borabicyclo[3.3.1]nonane
IUPAC传统名
(1s,5s)-9-borabicyclo[3.3.1]nonane
别名
9-BBN

产品登记号

CAS号 280-64-8
PubChem SID 24849089
Beilstein号 605509
MDL号 MFCD00074742

产品性质

浓度 0.5 M in THF
Empirical Formula (Hill Notation) C8H15B
密度 0.894 g/mL at 25 °C
闪点 -17 °C
闪点 1.4 °F
GHS危险品标识 GHS02
GHS危险品标识 GHS07
GHS警示词 Danger
GHS危险声明 H225-H260-H319-H335
欧盟危险性物质标志 易燃性(Flammable) 易燃性(Flammable) (F)
欧盟危险性物质标志 刺激性(Irritant) 刺激性(Irritant) (Xi)
MSDS下载 下载链接
GHS警示性声明 P210-P223-P231 + P232-P261-P370 + P378-P422
RID/ADR UN 3399 4.3/PG 1
危险公开号 11-14/15-19-36/37
安全公开号 16-26-43
欧盟补充危害声明 May form explosive peroxides.
联合国危险货物等级 4.3
联合国危险货物编号 3399
联合国危险货物包装类别(PG) 1
德国WGK号 3

产品详细信息

详细说明 (English)
Application
Differentiation of symmetrical diols by reduction of the corresponding cyclic acetals with 9-BBN.6
Selective hydroboration reduction reagent.
Protecting group for alkenes†Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives1
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides2
• Intramolecular insertion of alkenes into palladium-nitrogen bonds3
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast4
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids5
Packaging
4×25, 100, 800 mL in Sure/Seal™
8, 18 L in Kilo-Lab™
View returnable container options.
详细说明 (简体中文)
Application
使用 9-BBN 对相应环状缩醛进行还原以鉴别对称二醇。6
选择性硼氢化还原试剂。
Protecting group for alkenes†Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives1
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides2
• Intramolecular insertion of alkenes into palladium-nitrogen bonds3
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast4
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids5
包装
4×25, 100, 800 mL in Sure/Seal™
8, 18 L in Kilo-Lab™
View returnable container options.

参考文献