双(4-氯苄基)偶氮二甲酸酯

• 产品号: 680850
• CAS号: 916320-82-6
• 分子式: C16H12Cl2N2O4
• 分子量: 367.18348
• 纯 度: 97%

产品别名

• 标题: Di-(4-chlorobenzyl)azodicarboxylate
• IUPAC标准名: N-({[(4-chlorophenyl)methoxy]carbonyl}imino)[(4-chlorophenyl)methoxy]formamide
• IUPAC传统名: N-({[(4-chlorophenyl)methoxy]carbonyl}imino)[(4-chlorophenyl)methoxy]formamide
• 别名: DCAD; Bis(4-chlorobenzyl)azodicarboxylate; 偶氮二甲酸二(对氯苄基)酯

产品登记号

• CAS号: 916320-82-6
• PubChem SID: 24885598

产品性质

• Empirical Formula (Hill Notation): C16H12Cl2N2O4
• 纯度: 97%
• 熔点: 108-112 °C
• GHS警示词: Warning
• GHS危险声明: H317
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• GHS警示性声明: P280
• 危险公开号: 43
• 安全公开号: 36/37
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Di-(4-chlorobenzyl)azodicarboxylate (DCAD) is a novel, stable, solid alternative to DEAD and DIAD for a variety of Mitsunobu couplings giving a readily separable hydrazine byproduct that can be recycled.4
Reactant for preparation of:
• Amino thioesters via guanidine-catalyzed biomimetic enantioselective decarboxylative Mannich and amination reactions of malonic acid half thioesters1
• Hydroacylation reaction of aldehydes in Ionic liquid (IL) medium2
• DCAD (di-p-chlorobenzyl azodicarboxylate) for Mitsunobu coupling reactions3,4
Packaging
1, 10 g in glass bottle

详细说明 (简体中文)

Application
双(4-氯苄基)偶氮二甲酸酯 (DCAD) 是 DEAD 和 DIAD 的新型稳定固体替代物，可用于多种 Mitsunobu 偶联反应，生成易于分离并且可回收利用的副产物肼。4
Reactant for preparation of:
• Amino thioesters via guanidine-catalyzed biomimetic enantioselective decarboxylative Mannich and amination reactions of malonic acid half thioesters1
• Hydroacylation reaction of aldehydes in Ionic liquid (IL) medium2
• DCAD (di-p-chlorobenzyl azodicarboxylate) for Mitsunobu coupling reactions3,4
包装
1, 10 g in glass bottle