[2S-(2α,3β,8aβ)]-(+)-六氢-3-(羟甲基)-8a-甲基-2-苯基-5H-噁唑并[3,2-a]吡啶-5-酮

• 产品号: 388114
• CAS号: 116950-01-7
• 分子式: C15H19NO3
• 分子量: 261.31626
• 纯 度: 98%

产品别名

• 标题: [2S-(2α,3β,8aβ)]-(+)-Hexahydro-3-(hydroxymethyl)-8a-methyl-2-phenyl-5H-oxazolo[3,2-a]pyridin-5-one
• IUPAC标准名: (2R,3R,8aS)-3-(hydroxymethyl)-8a-methyl-2-phenyl-hexahydro-2H-[1,3]oxazolo[3,2-a]pyridin-5-one
• IUPAC传统名: (2R,3R,8aS)-3-(hydroxymethyl)-8a-methyl-2-phenyl-tetrahydro-2H-[1,3]oxazolo[3,2-a]pyridin-5-one

产品登记号

• PubChem SID: 24864208
• CAS号: 116950-01-7
• MDL号: MFCD00192204

产品性质

• Empirical Formula (Hill Notation): C15H19NO3
• 纯度: 98%
• 熔点: 96-100 °C(lit.)
• 比旋光度: [α]23/D +14°, c = 1 in ethanol
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves
• GHS警示性声明: P261-P305 + P351 + P338
• 危险公开号: 36/37/38
• 安全公开号: 26-36
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Chiral bicyclic lactams such as this are useful templates for asymmetric synthesis.1 High levels of asymmetric induction have been obtained in cycloadditions,2,3 alkylations,4,5,6 conjugate additions,7,8 annulations,9 and dihydroxylations.10
Packaging
5 g in glass bottle

详细说明 (简体中文)

Application
诸如此类的手性双环内酰胺是用于不对称合成的有用模板。1已在以下反应中实现了高水平的不对称诱导：环加成、2,3烷基化、4,5,6共轭加成、7,8成环、9以及双羟基化。10
包装
5 g in glass bottle