苯亚硒酸酐

• 产品号: L00795
• CAS号: 17697-12-0
• 分子式: C12H10O3Se2
• 分子量: 360.126
• 纯 度: tech. 70%

产品别名

• 标题: Benzeneseleninic anhydride
• IUPAC标准名: benzeneseleninyl benzeneseleninate
• IUPAC传统名: benzeneseleninyl benzeneseleninate
• 别名: Phenylseleninic anhydride

产品登记号

• MDL号: MFCD00001991
• CAS号: 17697-12-0
• EC号: 241-701-3
• Beilstein号: 2332406

产品性质

• 保存注意事项: Moisture Sensitive
• TSCA收录: 否
• 联合国危险货物等级: 6.1
• 联合国危险货物编号: UN3283
• 联合国危险货物包装类别(PG): II
• GHS危险声明: H301-H331-H373-H400-H410
• 欧盟危险性物质标志: 有毒(Toxic) (T)
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• GHS警示性声明: P273-P270-P302+P352-P309-P310-P501A
• 危险公开号: 23/25-33-50/53
• 安全公开号: 20/21-28-45-60-61
• 纯度: tech. 70%
• 熔点: 163-165°C (lit)

参考文献

• Selective oxidant which converts benzylic alcohols to aldehydes in high yield: J. Chem. Soc., Chem. Commun., 952 (1978); Tetrahedron Lett., 3331 (1979); J. Org. Chem., 46, 1442 (1981). Oxidizes phenols to o-quinones: J. Chem. Soc., Perkin 1, 1473 (1981): Tetrahedron, 44, 6397 (1988):
  
• Reagent for the dehydrogenation of ketones to ɑ?-enones and of cyclic enones to dienones: J. Chem. Soc., Perkin 1, 2209 (1980); J. Chem. Soc., Chem. Commun., 1044 (1981). δ-Lactones are also converted to their ɑ?-unsaturated derivatives: J. Chem. Soc., Perkin 1, 1919 (1982). Hydrazines can be converted to azo compounds; hydrazine itself gives diimide: J. Org. Chem., 46, 1564 (1981). 3-Substituted indolines give indoles: J. Chem. Soc., Perkin 1, 707 (1990).
• Monograph: Organoselenium Chemistry, D. Liotta, Ed., Wiley, N.Y. (1987).