酞菁钴(II)

• 产品号: 41496
• CAS号: 3317-67-7
• 分子式: C32H16CoN8
• 分子量: 571.45624

产品别名

• 标题: Cobalt(II) phthalocyanine
• IUPAC标准名: λ^2-cobalt(2+) ion 2,11,20,29,37,38,39,40-octaazanonacyclo[28.6.1.1^3,^1^0.1^1^2,^1^9.1^2^1,^2^8.0^4,^9.0^1^3,^1^8.0^2^2,^2^7.0^3^1,^3^6]tetraconta-1(36),2,4,6,8,10(40),11,13,15,17,19,21(38),22,24,26,28,30,32,34-nonadecaene-37,39-diide
• IUPAC传统名: λ^2-cobalt(2+) ion 2,11,20,29,37,38,39,40-octaazanonacyclo[28.6.1.1^3,^1^0.1^1^2,^1^9.1^2^1,^2^8.0^4,^9.0^1^3,^1^8.0^2^2,^2^7.0^3^1,^3^6]tetraconta-1(36),2,4,6,8,10(40),11,13,15,17,19,21(38),22,24,26,28,30,32,34-nonadecaene-37,39-diide
• 别名: Phthalocyanine cobalt(II) salt

产品登记号

• EC号: 222-012-7
• CAS号: 3317-67-7
• MDL号: MFCD00010718

产品性质

• 外观: Powder
• GHS危险声明: H341-H317
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• GHS警示性声明: P261-P280-P302+P352-P321-P405-P501A
• 危险公开号: 43-68
• 安全公开号: 36/37-60
• TSCA收录: 是

参考文献

• Catalyzes the reduction of alkenes, alkyl halides, nitro and nitroso groups with sodium borohydride in ethanol: Angew. Chem. Int. Ed., 20, 473 (1981).
• Readily forms crystalline Li or Na anions. The Li anion can be used for the selective reduction of both aliphatic and aromatic nitro groups to amines in the presence of olefinic, nitrile, carbonyl or aryl halide functionality. The reaction is useful in the Friedlaender quinoline synthesis, in which an ortho-nitro benzaldehyde is reduced in situ and reacted with an ɑ-methylene ketone: Angew. Chem. Int. Ed., 20, 208 (1981).