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三氟甲磺酸铟(III)

产品号 40131 公司名称 Alfa Aesar
CAS号 128008-30-0 公司网站 http://www.alfa.com
分子式 C3F9InO9S3 电 话
分子量 562.0253288 传 真
纯 度 99% min 电子邮件
保 存 Chembase数据库ID: 97718

产品价格信息

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产品别名

标题
Indium(III) trifluoromethanesulfonate
IUPAC标准名
indium(3+) ion tritrifluoromethanesulfonate
IUPAC传统名
indium(3+) ion tritriflate
别名
Indium triflate

产品登记号

MDL号 MFCD00144478
CAS号 128008-30-0

产品性质

纯度 99% min
外观 Powder
熔点 dec.
GHS危险品标识 GHS05
GHS危险声明 H314-H318
欧盟危险性物质标志 腐蚀性(Corrosive) 腐蚀性(Corrosive) (C)
GHS警示性声明 P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
危险公开号 34
安全公开号 26-36/37/39-45
保存注意事项 Hygroscopic
TSCA收录
联合国危险货物等级 8
联合国危险货物编号 UN3261
联合国危险货物包装类别(PG) II

产品详细信息

参考文献

  • Effective catalyst for tetrahydropyranylation and depyranylation of alcohols: Tetrahedron Lett., 43, 7975 (2002).
  • For a brief feature on uses of this reagent in synthesis, see: Synlett, 899 (2003).
  • Catalyst for efficient acylation of alcohols, phenols and amines, which can be acetylated in high yield with 0.1 mol% of catalyst: Synlett, 1743 (1999).
  • Also catalyzes intramolecular Diels-Alder reactions, with microwave irradiation; the catalyst is potentially reusable: Tetrahedron Lett., 41, 8639 (2000).
  • Catalyzes the dehydration of aldoximes to nitriles; ketoximes undergo the Beckmann rearrangement to give amides or lactams: Indian J. Chem., 41B, 154 (2002).
  • Catalyst for hetero Diels-Alder reactions, e.g. of 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, L14672 with imines: Tetrahedron Lett., 40, 5621 (1999):
  • Superior to Indium(III) chloride, L18758, for the sulfonylation of both activated and deactivated aromatic rings with arylsulfonyl chlorides: Synlett, 830 (2001).
  • Mild catalyst for the formation of 1,3-dithianes from carbonyl compounds with 1,3-Propanedithiol, A15261: Tetrahedron, 58, 7897 (2002), and of 1,3-oxathiolanes with 2-Mercaptoethanol, A15890: Synlett, 1535 (2002).
  • Superior to several other metal triflates in the Fridel-Crafts reaction of aromatic compounds with Methyl trifluoropyruvate, B21589: Synlett, 555 (2004).