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二羰基乙酰丙酮铑(I)_分子结构_CAS_14874-82-9)
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二羰基乙酰丙酮铑(I)

产品号 39295 公司名称 Alfa Aesar
CAS号 14874-82-9 公司网站 http://www.alfa.com
分子式 C7H7O4Rh 电 话
分子量 258.03358 传 真
纯 度 99% 电子邮件
保 存 Chembase数据库ID: 303332

产品价格信息

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产品别名

标题
Dicarbonyl(2,4-pentanedionato)rhodium(I)
IUPAC标准名
λ1-rhodium(1+) ion bis(methanidylidyneoxidanium) (2Z)-4-oxopent-2-en-2-olate
IUPAC传统名
λ1-rhodium(1+) ion bis(carbon monoxide) (2Z)-4-oxopent-2-en-2-olate
别名
Acetylacetonatorhodium(I) dicarbonyl
(Acetylacetonato)dicarbonylrhodium(I)

产品登记号

CAS号 14874-82-9
EC号 238-947-9
MDL号 MFCD00009884

产品性质

纯度 99%
外观 Crystalline
熔点 144-147°C subl.
溶解度 Soluble in acetone
GHS危险品标识 GHS02
GHS危险品标识 GHS06
GHS危险声明 H301-H319-H317-H228-H412
欧盟危险性物质标志 有毒(Toxic) 有毒(Toxic) (T)
欧盟危险性物质标志 易燃性(Flammable) 易燃性(Flammable) (F)
GHS警示性声明 P210-P241-P301+P310-P305+P351+P338-P405-P501A
危险公开号 11-25-36-43-53
安全公开号 20-24-26-37-45-60
TSCA收录
联合国危险货物等级 4.1
联合国危险货物编号 UN2926
联合国危险货物包装类别(PG) II

产品详细信息

参考文献

  • Miyaura has utilized this complex, in combination with a chelating phosphine ligand, for the conjugate addition of arylboronic acids to enones, to give saturated ketones: Organometallics, 16, 4339 (1997). Addition of aryl- and alkenylboronic acids to aldehydes to give secondary alcohols can also be brought about under similar conditions: Angew. Chem. Int. Ed., 37, 3279 (1998):
  • Catalyst for hydroformylation of alkenes with CO/H2 at atmospheric pressure to give enals: Angew. Chem. Int. Ed., 34, 1760 (1995).
  • An extension of these reactions to the addition of potassium alkenyl- and aryltrifluoroborates to aldehydes and enones has also been reported: Org. Lett., 1, 1683 (1999).