六水合四氟硼酸铜(II)

• 产品号: 26127
• CAS号: 72259-10-0
• 分子式: B2CuF8H2O
• 分子量: 255.1705056
• 纯 度: 98%

产品别名

• 标题: Copper(II) tetrafluoroborate hexahydrate
• IUPAC标准名: copper(2+) ion bis(tetrafluoroboranuide) hydrate
• IUPAC传统名: copper(2+) ion hydrate ditetrafluoroborate

产品登记号

• MDL号: MFCD00150223
• CAS号: 72259-10-0
• EC号: 253-959-4

产品性质

• 纯度: 98%
• 外观: Crystalline
• GHS危险声明: H314-H318
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• GHS警示性声明: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
• 危险公开号: 34
• 安全公开号: 26-36/37/39-45
• 保存注意事项: Hygroscopic
• TSCA收录: 是
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN3260
• 联合国危险货物包装类别(PG): III

参考文献

• Catalyst for acetylation of alcohols, phenols, thiols or amines with acetic anhydride, effective at 1 mol % under solvent-free conditions: Synthesis, 111 (2004). The method has also been applied to the formation of 1,1-diacetates from aldehydes: Synthesis, 831 (2004). Under similar conditions, conjugate addtion of thiols to ɑ,?-unsaturated carbonyl compounds can be effected: Tetrahedron Lett., 46, 1721 (2005). Catalyzes the ring-opening of epoxides by alcohols: Org. Lett., 4, 2817 (2002), or amines: Tetrahedron Lett., 46, 2675 (2005). Aldehydes and ketones are converted to their dimethyl or diethyl acetals in high yield with the corresponding orthoformates: Tetrahedron Lett., 46, 8319 (2005). Efficient conversion to 1,3-dithiolanes or 1,3-dithianes can also be achieved: Tetrahedron Lett., 46, 6213 (2005). Rapid and efficient formation of Boc derivatives of amines with Di-tert-butyl dicarbonate, A14708 has also been described: Tetrahdron Lett., 47, 1087 (2006).