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(1,5-环辛二烯)二氯化铱(I)二聚体_分子结构_CAS_12112-67-3)
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(1,5-环辛二烯)二氯化铱(I)二聚体

产品号 12749 公司名称 Alfa Aesar
CAS号 12112-67-3 公司网站 http://www.alfa.com
分子式 C16H24Cl2Ir2 电 话
分子量 671.70176 传 真
纯 度 Ir 57.2% 电子邮件
保 存 Chembase数据库ID: 140615

产品价格信息

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产品别名

标题
Chloro(1,5-cyclooctadiene)iridium(I) dimer
IUPAC标准名
bis(chloroiridium); bis(cycloocta-1,5-diene)
IUPAC传统名
bis(1,5-cyclooctadiene); bis(chloroiridium)
别名
Bis(1,5-cyclooctadiene)diiridium(I) dichloride

产品登记号

EC号 235-170-7
MDL号 MFCD00012414
CAS号 12112-67-3

产品性质

纯度 Ir 57.2%
外观 Crystalline powder
熔点 190°C dec.
溶解度 Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol.
TSCA收录

产品详细信息

参考文献

  • Catalyst precursor for asymmetric hydrogenation: Angew. Chem. Int. Ed., 37, 2897 (1998).
  • Effective catalyst for the reaction of alcohols with vinyl acetate to give vinyl ethers: J. Am. Chem. Soc., 124, 1590 (2002).
  • With catalytic amounts of dppp (1,3-Bis(diphenylphosphino)propane, A12931) and Cs2CO3, a transfer hydrogenation system with 2-propanol as the H source can reduce both olefinic double bonds and carbonyl groups; for ɑ?-unsaturated ketones, selective reduction to saturated ketones can be achieved: J. Org. Chem., 66, 4710 (2001).
  • In the presence of a phosphite, catalyzes displacements by carbon nucleophiles at the more substituted position in allylic systems: Angew Chem. Int. Ed., 36, 263 (1997); J. Am. Chem. Soc., 120, 8647 (1998).
  • Catalyst for Miyaura and Hartwig's direct boronylation of arenes with Bis(pinacolato)diboron, L16088: J. Am. Chem. Soc., 124, 390 (2002):