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乙酰丙酮铁(III)

产品号 12534 公司名称 Alfa Aesar
CAS号 14024-18-1 公司网站 http://www.alfa.com
分子式 C15H21FeO6 电 话
分子量 353.16864 传 真
纯 度 电子邮件
保 存 Chembase数据库ID: 107277

产品价格信息

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产品别名

标题
Iron(III) 2,4-pentanedionate
IUPAC标准名
iron(3+) ion tris((2Z)-4-oxopent-2-en-2-olate)
IUPAC传统名
iron(3+) ion tris((2Z)-4-oxopent-2-en-2-olate)
别名
Tris(acetylacetonato)iron(III)
Iron(III) acetylacetonate

产品登记号

Beilstein号 4157960
MDL号 MFCD00000020
CAS号 14024-18-1
EC号 237-853-5

产品性质

外观 Powder
熔点 ca 183°C dec.
GHS危险品标识 GHS06
GHS危险声明 H301-H319
欧盟危险性物质标志 X
GHS警示性声明 P280-P301+P310-P305+P351+P338-P321-P405-P501A
危险公开号 22-36
RTECS编号 NO8960000
安全公开号 26-36-60
TSCA收录

产品详细信息

参考文献

  • In combination with Na metal at room temperature in benzene, cyano groups are cleaved from alkyl nitriles to give the corresponding hydrocarbons: J. Am. Chem. Soc., 93, 7113 (1971).
  • Catalyst for the coupling of Grignard reagents with aryl halides: J. Am. Chem. Soc., 124, 13856 (2002); Org. Lett., 6, 1227 (2004), with vinyl sulfones to give alkenes: Tetrahedron Lett., 23, 2469 (1982); Tetrahedron, 44, 111 (1988), and with acyl halides to give ketones in good yield: Tetrahedron Lett., 25, 4805 (1984).Alkenyl halides couple with aryl Grignards to give 1-aryl alkenes: Synlett, 1901 (2001). For leading references and improved reaction conditions for the coupling of alkyl and aryl Grignards with a varirtety of enol triflates and acid chlorides, and also for selective monoalkylation of dichlroarenes and heteroarenes, see: J. Org. Chem., 69, 3743 (2004).
  • Catalyzes the nitration of non-activated arenes, e.g. halogenobenzenes, and moderately activated arenes, e.g. alkylbenzenes and naphthalenes under non-acidic, non-aqueous conditions with NO2 in the presence of O2; no nitration occurs in the absence of the Fe(III) catalyst: J. Chem. Soc., Perkin 1, 2385 (1996).