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氯化钯(II)_分子结构_CAS_7647-10-1)
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氯化钯(II)

产品号 11034 公司名称 Alfa Aesar
CAS号 7647-10-1 公司网站 http://www.alfa.com
分子式 Cl2Pd 电 话
分子量 177.326 传 真
纯 度 99.9% (metals basis), Pd 59.5% min 电子邮件
保 存 Chembase数据库ID: 64298

产品价格信息

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产品别名

标题
Palladium(II) chloride
IUPAC标准名
palladium(2+) ion dichloride
IUPAC传统名
palladium(2+) ion dichloride

产品登记号

MDL号 MFCD00003558
CAS号 7647-10-1
EC号 231-596-2
默克索引号 146990

产品性质

纯度 99.9% (metals basis), Pd 59.5% min
外观 Crystalline
密度 4.0
熔点 675°C dec.
溶解度 Soluble in dilute mineral acids, aqueous metal halides
GHS危险品标识 GHS05
GHS危险品标识 GHS07
GHS危险声明 H314-H318-H290-H317-H303
欧盟危险性物质标志 刺激性(Irritant) 刺激性(Irritant) (Xi)
GHS警示性声明 P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
危险公开号 41-43
RTECS编号 RT3500000
安全公开号 24-26-37/39-60
TSCA收录
联合国危险货物等级 8
联合国危险货物编号 UN3260
联合国危险货物包装类别(PG) III

产品详细信息

参考文献

  • In combination with benzoquinone as reoxidant, N-methylarylamines add to Michael acceptors to give enamines: J. Org. Chem., 46, 2561 (1981).
  • Terminal olefins can be oxygenated to ketones using a Cu(I) catalyst in the presence of a catalytic amount of PdCl2 (the Wacker process): Org. Synth. Coll., 7, 137 (1990). For an example in which the product is readily cyclized to give a useful terpenoid synthon, see: Org. Synth. Coll., 8, 208 (1993):
  • In the presence of triphenylphosphine and MeLi, a Pd(0) species is generated which catalyzes the coupling of organolithium reagents with aryl or vinyl halides. For tabulated results, see: Org. Synth. Coll., 7, 172 (1990):
  • For use in the microwave accelerated Heck coupling reaction of aryl halides in the ionic liquid 1-n-Butyl-3-methylimidazolium hexafluorophosphate, L19086, see: J. Org. Chem., 67, 6243 (2002).