您当前所在的位置:首页 > 产品中心 > 产品信息
(1,5-环辛二烯)氯化铑(I)二聚体_分子结构_CAS_12092-47-6)
点击图片或这里关闭

(1,5-环辛二烯)氯化铑(I)二聚体

产品号 10466 公司名称 Alfa Aesar
CAS号 12092-47-6 公司网站 http://www.alfa.com
分子式 C16H24Cl2Rh2 电 话
分子量 493.07876 传 真
纯 度 电子邮件
保 存 Chembase数据库ID: 126807

产品价格信息

请登录

产品别名

标题
Chloro(1,5-cyclooctadiene)rhodium(I) dimer
IUPAC标准名
bis(chlororhodium); bis(cycloocta-1,5-diene)
IUPAC传统名
bis(1,5-cyclooctadiene); bis(chlororhodium)
别名
Bis(1,5-cyclooctadiene)dirhodium(I) dichloride

产品登记号

EC号 235-157-6
CAS号 12092-47-6
MDL号 MFCD00012415

产品性质

外观 Crystalline
熔点 243°C dec.
溶解度 Sparingly soluble in most common solvents
保存注意事项 Air Sensitive & Hygroscopic
TSCA收录

产品详细信息

参考文献

  • Homogeneous catalyst and catalyst precursor. For use in the preparation of a chiral BINAP alkene isomerization catalyst, see: Org. Synth. Coll., 8, 183 (1993).
  • Catalyzes the dehydrogenative coupling reaction of styrenes with Pinacolborane, L17558 to give the corresponding vinylboronates: Tetrahedron Lett., 40, 2585 (1999); Bull. Chem. Soc. Jpn., 75, 825 (2002). The complex has also been found to promote the atmospheric pressure carbonylation of benzylic halides to give good yields of phenylacetic acids: Tetrahedron Lett., 41, 7601 (2000).
  • Miyaura has reported the Rh-catalyzed conjugate addition of arylboronic acids to ɑ?-unsaturated carbonyl compounds in a single aqueous phase: Chem. Lett., 722 (2001):