三特丁基膦

• 产品号: 10178
• CAS号: 13716-12-6
• 分子式: C12H27P
• 分子量: 202.316541
• 纯 度: 96%

产品别名

• 标题: Tri-tert-butylphosphine
• IUPAC标准名: tri-tert-butylphosphane
• IUPAC传统名: tri-tert-butylphosphane

产品登记号

• CAS号: 13716-12-6
• EC号: 237-266-4
• MDL号: MFCD00015006

产品性质

• 危险公开号: 17-34
• 安全公开号: 26-36/37/39-45
• 保存注意事项: Air & Moisture Sensitive
• TSCA收录: 否
• 联合国危险货物等级: 4.2
• 联合国危险货物编号: UN2845
• 联合国危险货物包装类别(PG): I
• GHS危险声明: H250-H252-H314-H318
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• GHS警示性声明: P210-P303+P361+P353-P305+P351+P338-P405-P422A-P501A
• 纯度: 96%
• 外观: Solid
• 沸点: 102-103°C/13mm
• 闪点: -16°C(-3°F)
• 熔点: 30°C

参考文献

• For a brief feature on uses of the reagent in synthesis, see: Synlett, 709 (2005).
• Ligand which has been used in conjunction with Tris(dibenzylideneacetone)dipalladium(0), 12760 in promoting Suzuki cross-coupling reactions of arylboronic acids with aryl and vinyl halides under mild conditions. The system is particularly recommended for coupling reactions with normally unreactive aryl chlorides: J. Am. Chem. Soc., 4070 (2000). The same catalyst system has been found to be effective in the room-temperature cyanation of aryl bromides using zinc cyanide: Synlett, 2237 (2003).
• Efficient catalyst for the trifluoromethylation of aldehydes, ketones, imides and imines with (Trifluoromethyl)trimethylsilane, B20347: Synlett, 267 (2006).