(R)-(+)-1-苯基乙胺

• 产品号: L19117
• CAS号: 3886-69-9
• 分子式: C8H11N
• 分子量: 121.17964
• 纯 度: ChiPros 99+%, ee 99+%

产品别名

• 标题: (R)-(+)-1-Phenylethylamine
• IUPAC标准名: (1R)-1-phenylethan-1-amine
• IUPAC传统名: D-α-methylbenzylamine
• 别名: D-(+)-alpha-Methylbenzylamine

产品登记号

• EC号: 223-423-4
• MDL号: MFCD00064405
• Beilstein号: 2410916
• 默克索引号: 146026
• CAS号: 3886-69-9

产品性质

• 纯度: ChiPros 99+%, ee 99+%
• 沸点: 187°C
• 密度: 0.948
• 闪点: 71°C(159°F)
• 熔点: -10°C
• 比旋光度: +30 (c=10 in ethanol)
• 折射率: 1.5260
• GHS危险声明: H301-H311-H314-H318-H227
• 欧盟危险性物质标志: X
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• GHS警示性声明: P210-P301+P310-P303+P361+P353-P305+P351+P338-P361-P405-P501A
• 危险公开号: 21/22-34
• 安全公开号: 26-36/37/39-45-60
• 保存注意事项: Air Sensitive
• TSCA收录: 是
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN2735
• 联合国危险货物包装类别(PG): II

参考文献

• For use in the enantioselective synthesis of ɑ-amino nitriles and amino acids in the Strecker reaction, see: Chem. Ber., 110, 2098 (1977); J. Org. Chem., 48, 5369 (1983). Similarly, the preformed imines can be reacted with Trimethylsilyl cyanide, A19598: Chem. Lett., 331, 737 (1975). Enantioselective synthesis of cyclohexylamines from 2-alkylcyclohexanones via the imine and reduction: Tetrahedron Lett., 22, 2633 (1981); Chem. Ber., 117, 2076 (1984). Enantioselective synthesis of ɑ-aminoacetals from 1,1-dialkoxy-2-propanones: Synthesis, 608 (1989).
• Both enantiomers are widely used resolving agent for chiral acids. They also find extensive use as chiral auxiliaries in asymmetric synthesis: