D-1,2:4,5-二邻异丙二烯-B-D-红-2,3-己基

• 产品号: L18989
• CAS号: 18422-53-2
• 分子式: C12H18O6
• 分子量: 258.26772
• 纯 度: 98%

产品别名

• 标题: D-Epoxone
• IUPAC标准名: (3aR,6S,7aR)-2,2,5',5'-tetramethyl-tetrahydro-2H-spiro[[1,3]dioxolo[4,5-c]pyran-6,2'-[1,4]dioxolane]-7-one
• IUPAC传统名: (3aR,6S,7aR)-2,2,5',5'-tetramethyl-dihydro-3aH-spiro[[1,3]dioxolo[4,5-c]pyran-6,2'-[1,4]dioxolane]-7-one
• 别名: 1,2:4,5-Di-O-isopropylidene-beta-D-erythro-2,3-hexodiulo-2,6-pyranose

产品登记号

• EC号: 000-000-0
• MDL号: MFCD00063383
• CAS号: 18422-53-2
• Beilstein号: 1319073

产品性质

• 纯度: 98%
• 熔点: 101-103°C
• TSCA收录: 否

参考文献

• Developed by Shi's group for the enantioselective epoxidation of alkenes. Used in substoichiometric amounts in the presence of Oxone^TM or hydrogen peroxide, a chiral dioxirane is formed which converts trans-disubstituted and trisubstituted alkenes to epoxides with high ee: J. Am. Chem. Soc., 119, 11224 (1997); Tetrahedron Lett., 40, 8721 (1999). Selective monoepoxidation of dienes: J. Org. Chem., 63, 2948 (1998), or enynes: Tetrahedron Lett., 39, 4425 (1998), can be achieved. Has also been applied to the kinetic resolution of racemic cyclic olefins: J. Am. Chem. Soc., 121, 7718 (1999).