1-氟-4-羟基-1,4-重氮化二环2.2.2辛烷双(四氟硼酸盐)

• 产品号: L17628
• CAS号: 162241-33-0
• 分子式: C6H13B2F9N2O
• 分子量: 321.7878488
• 纯 度: ca 45-50% w/w on alumina

产品别名

• 标题: 1-Fluoro-4-hydroxy-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)
• IUPAC标准名: 1-fluoro-4-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium; bis(tetrafluoroboranuide)
• IUPAC传统名: 1-fluoro-4-hydroxy-1,4-diazabicyclo[2.2.2]octane-1,4-diium ditetrafluoroborate
• 别名: Accufluor NFTh

产品登记号

• CAS号: 162241-33-0
• Beilstein号: 8369351
• MDL号: MFCD00467883
• EC号: 418-330-2

产品性质

• 纯度: ca 45-50% w/w on alumina
• GHS危险声明: H318-H373-H302-H317-H411-H401
• 欧盟危险性物质标志: X
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• GHS警示性声明: P260-P261-P305+P351+P338-P302+P352-P321-P501A
• 危险公开号: 22-41-43-48/22-51/53
• 安全公开号: 22-26-36/37/39-61
• TSCA收录: 否
• 联合国危险货物等级: 9
• 联合国危险货物编号: UN3077
• 联合国危险货物包装类别(PG): III

参考文献

• AccuFluor is a registered trademark of AlliedSignal Inc.
• Versatile, reactive electrophilic fluorinating agent which can be used in water or organic solvents. A variety of substrates such as ketones: Tetrahedron Lett., 37, 3591 (1996), aromatics and enol ethers or enol esters, including steroidal derivatives, can be fluorinated successfully under mild conditions: Tetrahedron Lett., 40, 2673 (1999):
  
• Active methylene compounds (?-diketonesand?-keto esters) are fluorinated in good yield in the presence of zinc chloride and imidazole or collidine. In the presence of water or alcohols, alkenes undergo hydroxy- or alkoxyfluorination to give fluorohydrin derivatives: Tetrahedron Lett., 36, 6769 (1995); 40, 2673 (1999).