丙烯基硼酸邻二叔醇酯

• 产品号: L16232
• CAS号: 72824-04-5
• 分子式: C9H17BO2
• 分子量: 168.04108
• 纯 度: 98+%

产品别名

• 标题: Allylboronic acid pinacol ester
• IUPAC标准名: 4,4,5,5-tetramethyl-2-(prop-2-en-1-yl)-1,3,2-dioxaborolane
• IUPAC传统名: 4,4,5,5-tetramethyl-2-(prop-2-en-1-yl)-1,3,2-dioxaborolane
• 别名: 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

产品登记号

• Beilstein号: 4244068
• MDL号: MFCD00013347
• CAS号: 72824-04-5

产品性质

• 纯度: 98+%
• 沸点: 50-53°C/5mm
• 密度: 0.890
• 闪点: 60°C(140°F)
• 折射率: 1.4270
• GHS危险声明: H226
• GHS警示性声明: P210-P241-P280-P303+P361+P353-P403+P235-P501A
• TSCA收录: 否
• 联合国危险货物等级: 3
• 联合国危险货物编号: UN3272
• 联合国危险货物包装类别(PG): III

参考文献

• Reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield: Synthesis, 1573 (2001):
  
• Homoallylic alcohols can also be formed by allylboration of aldehydes; the reaction has been found to be accelerated by Lewis acids, e.g. AlCl₃ or Sc(OTf)₃: J. Am. Chem. Soc., 124, 12414 (2002).