(1S,2S)-(+)-1,2-二苯基-1,2-乙二胺

• 产品号: L12968
• CAS号: 29841-69-8
• 分子式: C14H16N2
• 分子量: 212.29024
• 纯 度: 97%

产品别名

• 标题: (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine
• IUPAC标准名: (1S,2S)-1,2-diphenylethane-1,2-diamine
• IUPAC传统名: diphenylethylenediamine
• 别名: (1S,2S)-(-)-1,2-Diamino-1,2-diphenylethane; (1S,2S)-(-)-1,2-Diphenylethylenediamine

产品登记号

• Beilstein号: 3201645
• CAS号: 29841-69-8
• MDL号: MFCD00082751

产品性质

• 纯度: 97%
• 熔点: 80-84°C
• 比旋光度: -102 (c=1 in methanol)
• GHS危险声明: H314-H318
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• GHS警示性声明: P280-P305+P351+P338-P309-P310
• 危险公开号: 34
• 安全公开号: 26-36/37/39-45
• 保存注意事项: Air Sensitive
• TSCA收录: 否
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN3259
• 联合国危险货物包装类别(PG): III

参考文献

• Chiral auxiliary and solvation agent; see preceding entry.
• Co-catalyst in the Ru catalyzed enantioselective hydrogenation of aromatic ketones: J. Am. Chem. Soc., 117, 2675 (1995).
• For synthesis of enantiopure ethylenediamines by chirality transfer (condensation with diketones followed by reductive cleavage), see: J. Org. Chem ., 57, 6653 (1992).