三异丙基硅烷

• 产品号: L09585
• CAS号: 6485-79-6
• 分子式: C9H22Si
• 分子量: 158.35648
• 纯 度: 98%

产品别名

• 标题: Triisopropylsilane
• IUPAC标准名: tris(propan-2-yl)silane
• IUPAC传统名: triisopropylsilane
• 别名: TIS

产品登记号

• CAS号: 6485-79-6
• Beilstein号: 1733718
• MDL号: MFCD00009657

产品性质

• 纯度: 98%
• 沸点: 166°C
• 密度: 0.773
• 闪点: 35°C(95°F)
• 折射率: 1.4340
• GHS危险声明: H226-H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• GHS警示性声明: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• 危险公开号: 10-36/37/38
• 安全公开号: 23-26-37-60
• TSCA收录: 否
• 联合国危险货物等级: 3
• 联合国危险货物编号: UN1993
• 联合国危险货物包装类别(PG): III

参考文献

• Selective silylation of primary OH groups in the presence of secondary has been carried out with this reagent in combination with CsF and imidazole: J. Organomet. Chem., 282, 155 (1985). See Appendix 4.
• Triethylsilane and triisopropylsilane have been studied as cation scavengers in the deprotection of peptides with TFA, and were found to give good results, with triisopropylsilane being particularly effective in trapping trityl cations in the TFA deprotection of cysteine containing peptides. The use of triisopropylsilane minimizes the risk of reduction of the indole nucleus in tryptophan-containing peptides: Tetrahedron Lett., 30, 2739 (1989). See Appendix 6.