N,N-二甲基磷氨基二氯化物

• 产品号: L07231
• CAS号: 677-43-0
• 分子式: C2H6Cl2NOP
• 分子量: 161.954901
• 纯 度: 97%

产品别名

• 标题: N,N-Dimethylphosphoramidodichloridate
• IUPAC标准名: (dimethylamino)phosphonoyl dichloride
• IUPAC传统名: dimethylaminophosphonoyl dichloride
• 别名: N,N-Dimethylphosphoramic dichloride; Dimethylaminophosphoryl dichloride

产品登记号

• CAS号: 677-43-0
• Beilstein号: 969956
• EC号: 211-641-2
• MDL号: MFCD00013896

产品性质

• 纯度: 97%
• 沸点: 89-90°C/20mm
• 密度: 1.360
• 闪点: >110°C(230°F)
• 折射率: 1.4630
• GHS危险声明: H314-H318
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• GHS警示性声明: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
• 危险公开号: 34
• RTECS编号: TB4025000
• 安全公开号: 20-26-36/37/39-45
• 保存注意事项: Moisture Sensitive
• TSCA收录: 否
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN3265
• 联合国危险货物包装类别(PG): II

参考文献

• In the presence of pyridine, carboxylic acids form active intermediates which react with alcohols in situ to give esters: Tetrahedron Lett., 4461 (1978). Has also been used to convert primary alcohols to alkyl chlorides: Chem. Lett., 923 (1978).
• With 1,2-diols forms cyclic phosphoric amides which can be reduced to alkenes, e.g. with Na in xylene: Synth. Commun., 5, 293 (1975).