(苯硫基)三甲基硅烷

• 产品号: L06319
• CAS号: 4551-15-9
• 分子式: C9H14SSi
• 分子量: 182.35796
• 纯 度: 97%

产品别名

• 标题: (Phenylthio)trimethylsilane
• IUPAC标准名: trimethyl(phenylsulfanyl)silane
• IUPAC传统名: trimethyl(phenylsulfanyl)silane
• 别名: Phenyl trimethylsilyl sulfide; S-Trimethylsilylthiophenol

产品登记号

• MDL号: MFCD00008272
• CAS号: 4551-15-9
• EC号: 224-916-7
• Beilstein号: 1905944

产品性质

• 纯度: 97%
• 沸点: 73-75°C/10mm
• 密度: 0.965
• 闪点: 30°C(86°F)
• 折射率: 1.5320
• GHS危险声明: H226-H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• GHS警示性声明: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• 危险公开号: 10-36/37/38
• 安全公开号: 23-26-37
• 保存注意事项: Moisture Sensitive
• TSCA收录: 是
• 联合国危险货物等级: 3
• 联合国危险货物编号: UN1993
• 联合国危险货物包装类别(PG): III

参考文献

• Thioacetalization reagent. In the presence of CN^-, aldehydes and ketones are converted to O-TMS hemithioacetals J. Am. Chem. Soc., 99, 5009 (1977). With Lewis acids, e.g. TiCl₄, the diphenyl dithioacetals can be obtained in good yield J. Org. Chem., 55, 5966 (1990). Aldehydes and ketones can be converted to the otherwise difficultly accessible mixed O-alkyl, S-phenyl acetals by the reagent in the presence of the alkyl TMS ether and TMS triflate: Tetrahedron Lett., 32, 467 (1991).
• In the presence of TMS-OTf, converts methyl glycosides to phenylthio glycosides. These undergo methanolysis, after activation by reaction with NBS: J. Am. Chem. Soc., 105, 2430 (1983); 107, 1691 (1985).
• In the presence of ZnI₂ and tetrabutylammonium iodide, cleaves methyl and benzyl ethers in high yield: Tetrahedron Lett., 2305 (1980).