N,N,N',N'-四甲基亚甲二胺

• 产品号: L04037
• CAS号: 51-80-9
• 分子式: C5H14N2
• 分子量: 102.17806
• 纯 度: 99%

产品别名

• 标题: N,N,N',N'-Tetramethylmethylenediamine
• IUPAC标准名: [(dimethylamino)methyl]dimethylamine
• IUPAC传统名: [(dimethylamino)methyl]dimethylamine
• 别名: N,N,N'N'-Tetramethyldiaminomethane; Bis(dimethylamino)methane

产品登记号

• CAS号: 51-80-9
• MDL号: MFCD00008328
• EC号: 200-124-7
• Beilstein号: 1731946

产品性质

• 纯度: 99%
• 沸点: 83-85°C
• 密度: 0.749
• 闪点: -12°C(10°F)
• 熔点: -55°C
• 折射率: 1.4010
• GHS危险声明: H225-H314-H318
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• GHS警示性声明: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• 危险公开号: 11-34
• RTECS编号: PA6700000
• 安全公开号: 20-26-36/37/39-45-60
• TSCA收录: 是
• 联合国危险货物等级: 3
• 联合国危险货物编号: UN2733
• 联合国危险货物包装类别(PG): II

参考文献

• Has been used as a convenient source of the Mannich intermediate: J. Org. Chem., 33, 1719 (1968). For an example (dimethylaminomethyleneation of ferrocene), see: Org. Synth. Coll., 5, 434 (1973). Reaction with o-hydroxy ɑ-aryl acetophenones leads directly to isoflavanones: Synth. Commun., 29, 3895 (1999):
  
• Caution! Theproduct of double lithiation has been reported to explode on drying: Org. Process Res. Dev., 7, 1029 (2003).