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三(三苯基膦)二氯化钌(II)_分子结构_CAS_15529-49-4)
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三(三苯基膦)二氯化钌(II)

产品号 L00373 公司名称 Alfa Aesar
CAS号 15529-49-4 公司网站 http://www.alfa.com
分子式 C54H45Cl2P3Ru 电 话
分子量 958.832383 传 真
纯 度 97% 电子邮件
保 存 Chembase数据库ID: 126990

产品价格信息

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产品别名

标题
Dichlorotris(triphenylphosphine)ruthenium(II)
IUPAC标准名
λ2-ruthenium(2+) ion tris(triphenylphosphane) dichloride
IUPAC传统名
λ2-ruthenium(2+) ion tris(triphenylphosphine) dichloride
别名
Tris(triphenylphosphine)ruthenium(II) chloride

产品登记号

CAS号 15529-49-4
MDL号 MFCD00013077
EC号 239-569-7

产品性质

纯度 97%
熔点 132-134°C
保存注意事项 Air & Moisture Sensitive
TSCA收录

产品详细信息

参考文献

  • Versatile homogeneous isomerization, reduction and oxidation catalyst.
  • Homoallylic alcohols can be isomerized to allylic: J. Am. Chem. Soc., 118, 12867 (1996); Tetrahedron, 54, 5129 (1998).
  • In combination with ethylenediamine and KOH in 2-propanol, conventional hydrogenation of ketones can be accomplished: J. Am. Chem. Soc., 117, 2675 (1995); J. Org. Chem., 61, 4872 (1996). This combination is also effective for the selective reduction of aldehydes and ketones in the presence of alkenes, whereas only olefinic bonds can be reduced with the Ru complex alone: J. Am. Chem. Soc., 117, 10417 (1995):
  • Catalyzes hydrogenation of aromatic nitro compounds to amines; selective reduction is possible in the presence of halogen, ester, nitrile and even additional nitro groups: Tetrahedron Lett., 2163 (1975). Aliphatic nitro compounds are hydrogenated to amines under high pressure: J. Org. Chem., 40, 519 (1975). Also catalyzes the high-yield reduction of nitroarenes to amines, indoles to indolines, quinolines to 1,2,3,4-tetrahydroquinolines by formic acid and triethylamine: Bull. Chem. Soc. Jpn., 57, 2440 (1984).
  • Catalyzes the cyclization 2-aminophenethyl alcohols to indoles in high yield: J. Org. Chem., 55, 580 (1990):
  • Catalyst for the reaction of N-alkylanilines with triethanolamine in dioxan (autoclave) to give the corresponding 1-alkylindoles in good yield: Synth. Commun., 26, 1349 (1996).
  • In the presence of acetone, secondary alcohols can be oxidized to ketones: J. Chem. Soc., Chem. Commun., 337 (1992). For use in the dehydrogenation of amines to imines and the oxidation of cyanohydrins to acyl cyanides, see tert-Butyl hydroperoxide, A13926. In combination with hydroquinone, selective aerobic oxidation of a primary alcohol to an aldehyde, in the presence of a secondary alcohol, can be achieved: Tetrahedron Lett., 39, 5557 (1998).
  • Alkylated arenes can be oxidized to ketones by tert-butyl hydroperoxide, catalyzed by the complex: J. Org. Chem., 65, 9186 (2000).
  • In the presence of KOH, catalyzes the one-pot ɑ-alkylation of secondary alcohols with primary alcohols: Organometallics, 22, 3608 (2002).