对甲苯磺酸银(I)

• 产品号: L00307
• CAS号: 16836-95-6
• 分子式: C7H7AgO3S
• 分子量: 279.06188
• 纯 度: 98+%

产品别名

• 标题: Silver p-toluenesulfonate
• IUPAC标准名: silver(1+) ion 4-methylbenzene-1-sulfonate
• IUPAC传统名: silver(1+) ion tosylate
• 别名: Silver tosylate; p-Toluenesulfonic acid silver salt

产品登记号

• EC号: 240-859-0
• CAS号: 16836-95-6
• MDL号: MFCD00007511

产品性质

• 纯度: 98+%
• GHS危险声明: H400-H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• GHS警示性声明: P280G-P273-P305+P351+P338
• 危险公开号: 36/37/38-50
• 安全公开号: 26-37-61
• 保存注意事项: Light Sensitive
• TSCA收录: 是
• 联合国危险货物等级: 9
• 联合国危险货物编号: UN3077
• 联合国危险货物包装类别(PG): III

参考文献

• Silver salt soluble in many organic solvents; useful, e.g. in promotion of the leaving ability of halogens. For use in the conversion of alkyl halides to alkyl tosylates, see: J. Am. Chem. Soc., 81, 4113 (1959); J. Chem. Soc., 6748 (1965).
• Induces carbocation rearrangements in alkyl halides, e.g. promotes the stereospecific disrotatory ring-opening of the cyclopropyl cation resulting from ionization of gem-dibromocyclopropanes: J. Org. Chem., 41, 384 (1976).
• For conversion of benzylic bromides to styrenes, see: Bul. Chem. Soc. Jpn., 66, 589 (1993).