四正丙基过钌(VII)酸铵

• 产品号: B24511
• CAS号: 114615-82-6
• 分子式: C12H28NO4Ru
• 分子量: 351.42502
• 纯 度: 98%

产品别名

• 标题: Tetra-n-propylammonium perruthenate(VII)
• IUPAC标准名: tetrapropylazanium rutheniumoylolate
• IUPAC传统名: tetrapropylammonium rutheniumoylolate
• 别名: TPAP

产品登记号

• CAS号: 114615-82-6
• MDL号: MFCD00074914

产品性质

• 纯度: 98%
• 熔点: 160°C dec.
• GHS危险声明: H272-H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 欧盟危险性物质标志: 氧化性(Oxidising) (O)
• GHS警示性声明: P221-P210-P305+P351+P338-P302+P352-P405-P501A
• 危险公开号: 5-8-36/37/38
• 安全公开号: 17-26-37
• 保存注意事项: Hygroscopic
• TSCA收录: 否
• 联合国危险货物等级: 5.1
• 联合国危险货物编号: UN1479
• 联合国危险货物包装类别(PG): III

参考文献

• For a brief feature on uses in synthesis, see: Synlett, 824 (2007).
• Selective, catalytic oxidant introduced by Ley. Normally used in combination with N-methylmorpholine-N-oxide as the stoichiometric reoxidant and 4A molecular sieves to remove water. Preferred solvents are dichloromethane and acetonitrile. Primary and secondary alcohols are oxidized to aldehydes and ketones in high yield: J. Chem. Soc., Chem. Commun., 1625 (1987). For an example of alcohol to aldehyde oxidation in the partial synthesis of the acyl tetronic acid ionophore tetronasin, see: Tetrahedron Lett., 35, 319 (1994). Also useful for a number of other oxidations such as lactols to lactones and sulfides to sulfones. For oxidation of secondary amines to imines, and of hydroxylamines to nitrones, see: Tetrahedron Lett., 35, 6567, 6571 (1994).
• For a comprehensive review of this reagent, see: Synthesis, 639 (1994). For a review of ruthenium oxo-complexes as organic oxidants, see: Chem. Soc. Rev., 21, 179 (1992).