三异丙氧化氯钛

• 产品号: B21914
• CAS号: 20717-86-6
• 分子式: C9H21ClO3Ti
• 分子量: 260.58124
• 纯 度: 95%

产品别名

• 标题: Chlorotitanium triisopropoxide
• IUPAC标准名: titanium(4+) ion tris(propan-2-olate) chloride
• IUPAC传统名: titanium(4+) ion tris(propan-2-olate) chloride
• 别名: Titanium chloride triisopropoxide; Chlorotriisopropoxytitanium

产品登记号

• MDL号: MFCD00009861
• CAS号: 20717-86-6

产品性质

• 纯度: 95%
• 沸点: 63-66°C/0.1mm
• 密度: 1.091
• 闪点: 31°C(87°F)
• 熔点: 37-44°C
• GHS危险声明: H314-H318-H228
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• GHS警示性声明: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• 危险公开号: 11-34
• 安全公开号: 26-36/37/39-45
• 保存注意事项: Moisture Sensitive
• TSCA收录: 是
• 联合国危险货物等级: 8
• 联合国危险货物编号: UN2921
• 联合国危险货物包装类别(PG): II

参考文献

• Reacts with the Li enolates of ketones to give Ti(IV) enolates which undergo the aldol condensation with pronounced erythro-selectivity: Tetrahedron Lett., 22, 4691 (1981). This selectivity can be extended to aldehydes by using the Li derivatives of their N,N-dimethylhydrazones: Angew. Chem. Int. Ed., 21, 864 (1982).
• In combination with cyclopentylmagnesium bromide, forms a Ti(II) species which mediates the reaction of vinyltributyltin with esters or amides to give trisubstituted cyclopropylstannanes with high diastereoselectivity: J. Org. Chem., 63, 9135 (1998).