2-(叔-丁氧基碳酰胺)-2-苯乙腈

• 产品号: A18906
• CAS号: 58632-95-4
• 分子式: C13H14N2O3
• 分子量: 246.26186
• 纯 度: 98+%

产品别名

• 标题: Boc-ON
• IUPAC标准名: tert-butyl (E)-[cyano(phenyl)methylidene]amino carbonate
• IUPAC传统名: tert-butyl (E)-[cyano(phenyl)methylidene]amino carbonate
• 别名: 2-(Boc-oxyimino)-2-phenylacetonitrile; 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile

产品登记号

• MDL号: MFCD00001863
• Beilstein号: 2217296
• CAS号: 58632-95-4
• EC号: 261-370-9

产品性质

• 纯度: 98+%
• 熔点: 86-89°C
• GHS危险声明: H331-H302-H312-H315-H319-H335
• 欧盟危险性物质标志: X
• GHS警示性声明: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 危险公开号: 20/21/22-36/37/38
• RTECS编号: DA0513600
• 安全公开号: 9-26-36/37
• 保存注意事项: Moisture Sensitive
• TSCA收录: 是
• 联合国危险货物等级: 6.1
• 联合国危险货物编号: UN3439
• 联合国危险货物包装类别(PG): III

参考文献

• Reagent for the preparation of Boc-derivatives of amino acids, preferred on safety grounds to the unstable t-butyl azidoformate. In aqueous dioxane and in the presence of triethylamine as base, reaction is rapid at room temperature. The organic by-product, 2-hydroxyimino-2-phenylacetonitrile is easily removed by extraction into an organic phase: Tetrahedron Lett., 4393 (1975); Bull. Chem. Soc. Jpn., 50, 718 (1977). See Appendix 6.