过氧化苯甲酸叔丁酯

• 产品号: A17373
• CAS号: 614-45-9
• 分子式: C11H14O3
• 分子量: 194.22706
• 纯 度: 98%

产品别名

• 标题: tert-Butyl peroxybenzoate
• IUPAC标准名: tert-butyl benzenecarboperoxoate
• IUPAC传统名: benzoyl T-butyl peroxide
• 别名: tert-Butyl perbenzoate

产品登记号

• Beilstein号: 1342734
• CAS号: 614-45-9
• MDL号: MFCD00008802
• EC号: 210-382-2

产品性质

• 纯度: 98%
• 沸点: 75-76°C/0.2mm
• 密度: 1.042
• 闪点: 93°C(199°F)
• 熔点: 6-8°C
• 折射率: 1.4990
• GHS危险声明: H200-H242-H302-H315-H319-H227
• 欧盟危险性物质标志: X
• 欧盟危险性物质标志: 氧化性(Oxidising) (O)
• 欧盟危险性物质标志: 爆炸性(Explosive) (E)
• GHS警示性声明: P210-P305+P351+P338-P373-P401A-P410-P501A
• 危险公开号: 2-7-22-36/38
• RTECS编号: SD9450000
• 安全公开号: 3/7-14-26-36/37
• TSCA收录: 是
• 联合国危险货物等级: 5.2
• 联合国危险货物编号: UN3103
• 联合国危险货物包装类别(PG): II

参考文献

• For free-radical allylic benzoyloxylation of cyclohexene, promoted by CuBr, and references for preparation of benzoyloxy derivatives of other classes of compound including hydrocarbons, esters, ethers, sulfides, amides, etc., see: Org. Synth. Coll., 5, 70 (1973). The reaction with alkenes is also efficiently promoted by a complex of Cu(OTf)₂ with DBN or DBU: Tetrahedron Lett., 37, 8435 (1996). For a review of acyloxylation at carbon, see: Synthesis, 1 (1972).
• In the presence of CuBr, effects dehydrogenation of oxazolines and thioazolines to the aromatized systems: J. Org. Chem., 61, 8207 (1996).
• Promotes Pd-catalyzed oxidative coupling of electron-rich aromatics with electron-deficient alkenes: Tetrahedron, 40, 2699 (1984).
• Promotes the free-radical addition of bisulfite to vinyltrimethylsilane, in an improved preparation of 2-(TMS)ethanesulfonyl chloride: Org. Synth., 75, 161 (1997).