一水合乙酸铜(II)

• 产品号: A16203
• CAS号: 6046-93-1
• 分子式: C4H8CuO5
• 分子量: 199.64932
• 纯 度: 98+%

产品别名

• 标题: Copper(II) acetate monohydrate
• IUPAC标准名: copper(2+) ion diacetate hydrate
• IUPAC传统名: copper(2+) ion diacetate hydrate
• 别名: Cupric acetate; Acetic acid copper(II) salt

产品登记号

• CAS号: 6046-93-1
• EC号: 205-553-3
• MDL号: MFCD00149570
• 默克索引号: 142624

产品性质

• 纯度: 98+%
• 密度: 1.882
• 熔点: 115°C
• GHS危险声明: H400-H410-H302-H315-H319-H335
• 欧盟危险性物质标志: X
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• GHS警示性声明: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 危险公开号: 22-36/37/38-50/53
• RTECS编号: AG3500000
• 安全公开号: 26-36/37-57-60
• TSCA收录: 是
• 联合国危险货物等级: 9
• 联合国危险货物编号: UN3077
• 联合国危险货物包装类别(PG): III

参考文献

• Used in formation of Cu chelates of ?-dicarbonyl compounds as a means of purification, see, e.g.: Org. Synth. Coll., 3, 16, 292, 390 (1955).
• For use in the Eglinton (modified Glaser) coupling of terminal alkynes, see: Org. Synth. Coll., 5, 517 (1973); for intramolecular example in the synthesis of [18]annulene, see: Org. Synth. Coll., 6, 68 (1988).
• Useful catalyst for the Michael reaction giving increased yields and absence of side-reactions: Gazz. Chim. Ital., 114, 417 (1984).
• Promotes Ullmann-type C-O and C-N coupling reactions of arylboronic acids with phenols, amines and various other nitogen derivatives: Tetrahedron Lett., 39, 2933, 2937, 2941, 7979 (1998). Similar coupling reactions with thiols to give thioethers have also been reported: Org. Lett., 2, 2019 (2000).