二苯氯化碘鎓,

• 产品号: A15149
• CAS号: 1483-72-3
• 分子式: C12H10ClI
• 分子量: 316.56527
• 纯 度: 98+%

产品别名

• 标题: Diphenyliodonium chloride
• IUPAC标准名: diphenyliodanium chloride
• IUPAC传统名: diphenyliodanium chloride

产品登记号

• CAS号: 1483-72-3
• MDL号: MFCD00011909
• 默克索引号: 147464
• Beilstein号: 3574977
• EC号: 216-049-8

产品性质

• 纯度: 98+%
• 熔点: ca 230°C dec.
• GHS危险声明: H301-H315-H319-H335
• 欧盟危险性物质标志: 有毒(Toxic) (T)
• GHS警示性声明: P261-P301+P310-P305+P351+P338-P302+P352-P405-P501A
• 危险公开号: 25-36/37/38
• RTECS编号: NN6651666
• 安全公开号: 26-36/37-45
• 保存注意事项: Light Sensitive
• TSCA收录: 是
• 联合国危险货物等级: 6.1
• 联合国危险货物编号: UN2811
• 联合国危险货物包装类别(PG): III

参考文献

• They are also useful phenylating agents for a variety of anions:
• Diphenyliodonium salts are widely used as photoinitiators for cationic polymerization: Macromolecules, 10, 1307 (1977); review: Adv. Polym. Sci., 62, 1 (1982).
• C-Phenylation of the anions derived from malonic esters, ?-keto esters and arylacetic esters: J. Org. Chem., 28, 714 (1963). Arylation of ketones: J. Org. Chem., 31, 4315 (1966). ?-Diketones can be arylated either as monoanions: Tetrahedron, 8, 49 (1960); J. Am. Chem. Soc., 84, 2819 (1962), or as dianions: J. Org. Chem., 29, 3514 (1964), where reaction occurs at the more reactive (terminal) carbon; see, e.g. (1-phenylation of 2,4-pentanedione): Org. Synth. Coll., 6, 928 (1988). For arylation of Grignard reagents and cyanide ion, see: J. Am. Chem. Soc., 75, 2708 (1953), and of nitro-compounds: J. Org. Chem., 28, 1424 (1963); 29, 2108 (1964). Other reactions reported include: O-Phenylation of aryloxides: J. Chem. Soc., 2645 (1961), alkoxides and oximes: J. Org. Chem., 40, 3010 (1975); 36, 1780 (1971); S-Phenylation of sulfides: J. Org. Chem., 36, 233 (1971); N-Phenylation of heterocycles: Tetrahedron, 1, 145 (1957); J. Org. Chem., 39, 2710 (1974).
• For reviews of polyvalent iodine compounds in organic synthesis, see: Synthesis, 709 (1984); Chem. Rev., 96, 1123 (1996). For monographs, see: A. Varvoglis, The Organic Chemistry of Polycoordinated Iodine, VCH, N.Y. (1992); A. Varvoglis, Hypervalent Iodine in Organic Synthesis, Academic Press, San Diego (1996).