丙二腈

• 产品号: A15046
• CAS号: 109-77-3
• 分子式: C3H2N2
• 分子量: 66.06138
• 纯 度: 99%

产品别名

• 标题: Malononitrile
• IUPAC标准名: propanedinitrile
• IUPAC传统名: malononitrile
• 别名: Propanedinitrile; Dicyanomethane

产品登记号

• MDL号: MFCD00001883
• Beilstein号: 773697
• EC号: 203-703-2
• 默克索引号: 145711
• CAS号: 109-77-3

产品性质

• 溶解度: Soluble in water
• 沸点: 220-222°C
• 密度: 1.049
• 闪点: 112°C(233°F)
• 熔点: 30-34°C
• 折射率: 1.4150
• GHS危险声明: H301-H311-H331-H400-H410
• 欧盟危险性物质标志: 有毒(Toxic) (T)
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• GHS警示性声明: P261-P301+P310-P361-P302+P352-P405-P501A
• 危险公开号: 23/24/25-50/53
• RTECS编号: OO3150000
• 安全公开号: 23-27-45-60-61
• TSCA收录: 是
• 联合国危险货物等级: 6.1
• 联合国危险货物编号: UN2647
• 联合国危险货物包装类别(PG): II
• 纯度: 99%

参考文献

• Reviews of the chemistry of malononitrile: Chem. Rev., 69, 591 (1969); Synthesis, 165, 241 (1978); 925 (1981); Synlett, 2247 (2004).
• The Na derivative can be arylated by reaction with aryl halides with a Pd catalyst: J. Chem. Soc., Chem. Commun., 932 (1984). In the presence of butadiene, an additional 4-carbon unit is introduced: J. Chem. Soc., Perkin 1, 647 (1990):
  
• Ternary condensation with an aromatic aldehyde and a cycloalkanone in the presence of ammonium acetate can give a variety of products. With cyclohexanone, the 2-amino-4-aryl-5,6,7,8-tetrahydroquinoline-3-carbonitriles are the major products: J. Chem. Res. (Synop.), 146 (1995).