乙酰丙酮铜(II)

• 产品号: A14920
• CAS号: 13395-16-9
• 分子式: C10H14CuO4
• 分子量: 261.76176
• 纯 度: 98%

产品别名

• 标题: Copper(II) 2,4-pentanedionate
• IUPAC标准名: (3E)-4-[({[(2E)-4-oxopent-2-en-2-yl]oxy}cuprio)oxy]pent-3-en-2-one
• IUPAC传统名: (3E)-4-[({[(2E)-4-oxopent-2-en-2-yl]oxy}cuprio)oxy]pent-3-en-2-one
• 别名: Bis(2,4-pentanedionato)copper(II); Bis(acetylacetonato)copper(II)

产品登记号

• EC号: 236-477-9
• CAS号: 13395-16-9
• MDL号: MFCD00000016
• Beilstein号: 4157957

产品性质

• 纯度: 98%
• 沸点: 160°C/10mm
• 熔点: ca 286°C dec.
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• GHS警示性声明: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 危险公开号: 36/37/38
• RTECS编号: GL6520000
• 安全公开号: 26-37
• TSCA收录: 是

参考文献

• Catalyst for the carbenoid reaction of diazoacetate esters with silyl enol ethers to give siloxycyclopropanes: Liebigs Ann. Chem., 512 (1984); Org. Synth. Coll., 9, 573 (1998).
• In catalytic amounts promotes the selective O-benzylation of primary alcohols with benzyl chloride, in the presence of secondary alcohols or phenols: Tetrahedron Lett., 44, 8483 (2003). For a brief feature on uses of the reagent in synthesis, see: Synlett, 2859 (2005).
• The most effective of a number of metal chelates studied in enabling the reduction of aromatic nitro-compounds by sodium borohydride: J. Chem. Soc., Perkin 1, 2409 (1979).
• Promotes the coupling of organozinc reagents with allylic halides to give , δ-unsaturated esters: Tetrahedron Lett., 24, 2749 (1983).