烯丙基氯

• 产品号: A14330
• CAS号: 107-05-1
• 分子式: C3H5Cl
• 分子量: 76.5248
• 纯 度: 98%, stab. with propylene oxide

产品别名

• 标题: Allyl chloride
• IUPAC标准名: 3-chloroprop-1-ene
• IUPAC传统名: allyl chloride
• 别名: 3-Chloro-1-propene

产品登记号

• MDL号: MFCD00000984
• EC号: 203-457-6
• CAS号: 107-05-1
• Beilstein号: 635704
• 默克索引号: 14289

产品性质

• 纯度: 98%, stab. with propylene oxide
• 沸点: 44-46°C
• 密度: 0.939
• 闪点: -28°C(-18°F)
• 熔点: -135°C
• 折射率: 1.4160
• GHS危险声明: H225-H341-H351-H373-H400-H302-H312-H332-H315-H319-H335
• 欧盟危险性物质标志: X
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N)
• GHS警示性声明: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• 危险公开号: 11-20/21/22-36/37/38-40-48/20-68-50
• RTECS编号: UC7350000
• 安全公开号: 2-16-25-26-36/37-46-61
• TSCA收录: 是
• 联合国危险货物等级: 3
• 联合国危险货物编号: UN1100
• 联合国危险货物包装类别(PG): I

参考文献

• Lithiation with LDA in THF at -78^o generatesɑ-chloroallyllithium which can be ɑ-alkylated with primary bromides in high yield. Displacement of the resulting allylic chloride with a dialkyl cuprate to give, stereoselectively, an (E)-alkene, has been used in a pheromone synthesis: J. Org. Chem., 45, 1504 (1981).
• Treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene. For details and Diels-Alder reactions, see: J. Org. Chem., 61, 6462 (1996).