双(三苯基膦)硼氢化铜(I)

• 产品号: A13730
• CAS号: 16903-61-0
• 分子式: C36H33BCuP2
• 分子量: 601.951742

产品别名

• 标题: Bis(triphenylphosphine)copper(I) borohydride
• IUPAC标准名: λ^1-copper(1+) ion bis(triphenylphosphane) boranuide
• IUPAC传统名: λ^1-copper(1+) ion bis(triphenylphosphine) boranuide
• 别名: Tetrahydridoboratobis(triphenylphosphine)copper(I); Bis(triphenylphosphine)copper(I) tetrahydridoborate

产品登记号

• MDL号: MFCD00013219
• EC号: 240-951-0
• CAS号: 16903-61-0

产品性质

• 熔点: ca 175°C dec.
• GHS危险声明: H261-H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• GHS警示性声明: P231+P232-P305+P351+P338-P302+P352-P321-P405-P501A
• 危险公开号: 15-36/37/38
• 安全公开号: 8-26-37-43
• 保存注意事项: Moisture Sensitive
• TSCA收录: 否
• 联合国危险货物等级: 4.3
• 联合国危险货物编号: UN2813
• 联合国危险货物包装类别(PG): III

参考文献

• Specific reagent for reduction of acid chlorides to aldehydes: Tetrahedron Lett., 1437 (1978); 975 (1979). Also reduces sulfonylhydrazones to alkanes: Tetrahedron Lett., 4031 (1980), and aryl azides to amines: J. Chem. Res. (Synop.), 17 (1981).
• In the presence of Lewis acids or HCl, reduces carbonyl compounds with good stereo- and chemo-selectivity, e.g. aldehydes in the presence of ketones: Tetrahedron Lett., 22, 675 (1981).