2-乙氧基-1-乙氧基羰基-1,2-二氢喹啉

• 产品号: A13724
• CAS号: 16357-59-8
• 分子式: C14H17NO3
• 分子量: 247.28968
• 纯 度: 99%

产品别名

• 标题: 2-Ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline
• IUPAC标准名: ethyl 2-ethoxy-1,2-dihydroquinoline-1-carboxylate
• IUPAC传统名: ethyl 2-ethoxy-2H-quinoline-1-carboxylate
• 别名: EEDQ; N-Ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline

产品登记号

• 默克索引号: 143518
• Beilstein号: 533048
• EC号: 240-418-2
• CAS号: 16357-59-8
• MDL号: MFCD00006703

产品性质

• 纯度: 99%
• 沸点: 125-128°C/0.1mm
• 熔点: 63-66°C
• GHS危险声明: H315-H319-H335
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• GHS警示性声明: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 危险公开号: 36/37/38
• RTECS编号: VB2010000
• 安全公开号: 26-37
• 保存注意事项: Moisture Sensitive
• TSCA收录: 是

参考文献

• Reagent for peptide coupling. Reaction proceeds via the anhydride of the acid component: J. Am. Chem. Soc., 90, 823, 1651 (1968); Int. J. Pept. Prot. Res., 26, 493 (1985). See Appendix 6.
• For activation of ɑ -hydroxy acids, see: Tetrahedron Lett, 40, 3435 (1999) . Also used for the mild esterification of alcohols, e.g. for introduction of the levulinate protecting group (see Levulinic acid, A10813): Tetrahedron Lett., 23, 2615 (1982). For a useful esterification technique applicable to primary, secondary and tertiary alcohols, see: J. Org. Chem., 60, 7072 (1995).